herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl)

专利摘要:
HERBICIDIC COMPOSITIONS COMPRISING ACID4-AMINO-3-CHLORINE-5-FLUORO-6- (4-CHLORINE-2-FLUORO-3-METO-XYPHENYL) PYRIDINE-2-CARBOXYLIC, OR A DERIVATIVE FROM THE SAME, AND HALOSULFURONIC, AND HALOSULFURON, The present invention relates to synergistic herbicidal compositions containing, and methods of controlling undesirable vegetation using (a) a compound of formula (I): (I) or an agriculturally acceptable salt, or ester thereof, and (b ) halosulfuron-methyl, pyrazosulfuron-ethyl or esprocarb, or agriculturally acceptable derivatives thereof. The compositions and methods provided here provide control of undesirable vegetation, for example, in direct sown rice, sown in water, and transplanted, cereals, wheat, barley, oats, rye, sorghum, sauce, sugar cane, sunflower , rapeseed, canola, sugar beet, soy, cotton, pineapple, rapeseed, vegetables, pasta, grasslands, grazing land, "fallowland", peat, vineyards and orchards, cultivate water crops, vegetables, water control industrial vegetation (IVM), or rights of use (ROW).
公开号:BR102013018660B1
申请号:R102013018660-0
申请日:2013-07-22
公开日:2020-10-27
发明作者:Richard Mann；Carla Yerkes
申请人:Dow Agrosciences Llc；
IPC主号:

专利说明:

Priority Claim
[001] This application claims the benefit of provisional patent application number 61 / 675,110, filed on July 24, 2012, and patent application number 13 / 834,326, filed on March 15, 2013, the description of each of which is incorporated herein by reference in its entirety. Field
[002] The present invention relates to herbicidal compositions comprising (a) 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid, or an agriculturally acceptable ester or salt thereof, and (b) halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt or ester thereof.
[003] Unwanted vegetation control methods comprising application of (a) 4- amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2 are also provided herein - carboxylic, or an agriculturally acceptable ester, or salt thereof, and (b) halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt or ester thereof. Background
[004] The protection of crops from weeds and other vegetation that inhibit crop growth is a constantly recurring problem in agriculture. To help combat this problem, researchers in the field of synthetic chemistry have produced an extensive variety of chemicals and chemical formulations that are effective in controlling such unwanted growth. Chemical herbicides of many types have been described in the literature, and a large number are in commercial use. However, there remains a need for compositions and methods that are effective in controlling undesirable vegetation. summary
ou um sal agricolamente aceitável ou éster do mesmo, e (b) seleciona-dos a partir do grupo consistindo em halosulfuron-metila, pirazosulfu- ron-etila ou esprocarb, ou um sal agricolamente aceitável ou éster do mesmo.[005] A first embodiment of the invention provided herein includes herbicidal compositions comprising a herbicidally effective amount of (a) a compound of Formula (I) or an agriculturally acceptable salt or ester thereof, and (b) selected from the group consisting of halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt or ester thereof.
[006] A second embodiment includes mixing the first embodiment of Formula (I) in which it is present in the form of at least one of the following forms: a carboxylic acid, a carboxylate salt, an aralkyl, an alkyl ester, a non benzyl substituted, a substituted benzyl, a C1-4 alkyl, and / or an n-butyl ester.
[007] A third embodiment includes mixtures according to any of the first or second embodiment in which (b) is halosulfuron-methyl, in which the weight ratio of the compound of Formula (I) to halosulfuron-methyl given in units of gae / ha to gai / ha or gae / ha to gae / ha is selected from the group of ratios of ratios and ratios consisting of about: 1:70 to 214: 1, 1: 8 to 19: 1, 1: 1 to 2.4: 1, 1/2 to 1/3, 1: 1, 1: 2, 1: 4, 1: 1.7; 1: 0.75, 2: 1, 1: 5.7, 1: 0.8; and 1: 0.4, or within any defined range between any pair of the preceding values.
[008] A fourth embodiment includes mixtures according to any of the first or second embodiments in which (b) is pyrazosulfuron-ethyl, in which the weight ratio of the compound of Formula (I) to pirazosulfuron-ethyl given in units gae / ha to gai / ha or gae / ha to gae / ha, is selected from the group of ratios of ratios and ratios consisting of about: 1:60 to 600: 1, 1:27 to 4: 1, 0.8: 1 to 1: 6, 1: 4 to 4: 1, 1: 1 to 1: 3, 1: 5.7, 1: 3.4, 1: 6.8, 1:14, 1: 7, 1: 1.7; 1: 0.8; 1: 2, 1: 1, 2: 1, and 1: 4, or within any defined range between any pair of preceding values.
[009] A fifth embodiment includes mixtures according to any of the first or second embodiment in which (b) is espro-carb, in which the weight ratio of the compound of Formula (I) to espro-carb is given in units of gae / ha for gai / ha or gae / ha for gae / ha, is selected from the group of ratios of ratios and ratios consisting of about: 1: 500 to 6.1, 1:48 to 1: 3, 1: 12 to 1:24, 1: 6 to 1:12, 1:12, 1: 6, 1:24, and 1:48, or within any defined range between any pair of preceding values.
[0010] A sixth embodiment includes any composition according to any of the first to fifth embodiments, in which the mixture additionally comprises at least one agriculturally acceptable agent selected from the group consisting of an adjuvant, a vehicle, or an agricultural agent. protection.
[0011] A seventh embodiment includes methods of controlling undesirable vegetation comprising the step of applying or otherwise contacting the vegetation and / or soil, and / or water, with a herbicidally effective amount of at least one mixture according to any of the first to sixth embodiments.
[0012] An eighth embodiment includes methods according to the seventh embodiment, in which the method is practiced on at least one member of the group consisting of rice directly sown, sown in water, and / or transplanted, cereals, wheat, barley, oats , rye, sorghum, maize / maize, sugar cane, sunflower, rapeseed, canola, sugar beet, soy, cotton, pineapple, pasture, grassland, pasture land, fallow, peat, vineyards and orchards, aquatic plantation crops, plant management, industrial vegetation management (IVM), or easements of passage (ROW).
[0013] A ninth embodiment includes methods according to any of the seventh and eighth embodiments in which a herbicidally effective amount of the mixture is applied either pre- or post-emergently to at least one of the following: a crop, a field, a ROW, or a rice field.
[0014] A tenth embodiment includes methods according to any of the seventh to ninth embodiments, in which undesirable vegetation can be controlled in: glyphosate, 5-enolpyruvylshikimato-3-phosphatase (EPSP) synthase, glufosinate, inhibitor glutamine synthetase, dicamba, phenoxy auxin, pyridyloxy auxin, synthetic auxin, auxin transport inhibitor, aryloxyphenoxypropionate, cyclohexanedione, phenylpyrazoline, acetyl CoA carboxylase (ACCase), imidazolinone, sulfonylamide, sulfonylamine, trioxide, sulfonylamine, pyridine acetolactate synthase (ALS) or acetohydroxy acid synthase (AH-AS), 4-hydroxyphenylpyruvate dioxigenase (HPPD) inhibitor, phytene desaturase inhibitor, carotenoid biosynthesis inhibitor, protoporphyrinogen oxidase inhibitor (PPO), inhibitor cellulose biosynthesis, mitosis inhibitor, microtubule inhibitor, very long chain fatty acid inhibitor, bi inhibitor ossynthesis of fatty acid and lipid, photosystem I inhibitor, photosystem II inhibitor, protoporphyrinogen oxidase (PPO) inhibitor, triazine, or bromoxin-tolerant crops.
[0015] An eleventh embodiment includes at least one method according to any of the seventh to eleventh embodiments, in which a plant that is resistant or tolerant to at least one herbicide is treated, and in which the resistant or tolerant cultivation is treated multiple or stacked which give tolerance to multiple herbicides, or inhibitors of multiple modes of action; in some embodiments, the treated plant that expresses resistance or tolerance to an herbicide is undesirable vegetation.
[0016] A twelfth embodiment includes methods according to the eleventh embodiment, wherein the resistant or tolerant weed is a biotype with resistance or tolerance to multiple herbicides, multiple chemical classes, inhibitors of multiple herbicide modes of action, or via multiple resistance mechanisms.
[0017] A thirteenth embodiment includes at least one of the methods according to any of the eleventh or twelfth embodiment, in which the resistant or tolerant undesirable plant is a resistant or tolerant biotype to at least one agent selected to from groups consisting of: acetolactate synthase (ALS) inhibitors or acetohydroxy acid synthase (AHAS), photosystem II inhibitors, acetyl CoA carboxylase inhibitors (ACCase), synthetic auxins, auxin transport inhibitors, inhibitors of photosystem I, 5-enolpyruvylshikimato-3-phosphate (EPSP) synthase inhibitors, microtubule set inhibitors, fatty acid and lipid synthesis inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, carotenoid biosynthesis inhibitors, fatty acid inhibitors very long-chain (VLCFA), phytene desaturase (PDS) inhibitors, glutamine synthetase inhibitors, 4-hydroxyphenyl-pyruvate-dioxigenase (HPPD) inhibitors, inhibitors of mitosis, cellulose biosynthesis inhibitors, herbicides with multiple modes of action, quinclorac, arylaminopropionic, difenzoquat, endotal, or organoarsenic acids.
[0018] A fourteenth embodiment includes methods of controlling undesirable vegetation comprising the step of applying a herbicidally effective amount of at least one mixture according to the thirteenth embodiment, wherein the amount of the mixture is applied at a rate, expressed in g ai / ha or g ae / ha of ha-losulfuron-methyl selected from the group of rates and ranges consisting of about: 1, 2, 4.38, 8.75, 17.5, 35 and 70 , or within any defined range between any pair of preceding values.
[0019] A fifteenth embodiment includes methods according to any of the third and fourteenth embodiments, in which the controlled plant is at least one plant selected from the group consisting of: BRAPP, DIGSA, LEFCH, ECHOR, SCPMA, ECHCG, and CYPRO; yet other embodiments include control plants from the genus consisting of: Urochloa, Brachiaria, Digitaria, Bolboschoenus, Leptochloa, Echinochloa, Cyperus.
A sixteenth embodiment includes methods of controlling undesirable vegetation comprising the step of applying a herbicidally effective amount of at least one mixture according to the fourth embodiment, wherein the amount of the mixture is applied at a rate, expressed in g ai / ha or g ae / ha of pirazosulfuron-ethyl selected from the group of rates and ranges consisting of about: 5, 7.5, 10, 15, 17.5, 15, 30, 35, 60, 70, and 120, or within any defined range between any pair of the preceding values.
[0021] A seventeenth embodiment includes methods according to any of the fourth and sixteenth embodiments, in which the controlled plant is at least one plant selected from the group consisting of: CYPDI, ECHCG, ECHOR, SCPMA, DIGSA, BRAPP and LEFCH; yet other embodiments include control plants from the genus consisting of: Cyperus, Brachiaría, Digitaria, Echinochloa, Bolboschoenus, and Leptochloa.
[0022] An eighteenth embodiment includes methods of controlling undesirable vegetation comprising the step of applying a herbicidally effective amount of at least one mixture according to the fifth embodiment in which the amount of the mixture is applied at a rate, expressed in g ai / ha or g ae / ha of esprocarb selected from the group of rates and ranges consisting of about: 52.5, 105, and 210, or within any range defined between any pair of the preceding values.
[0023] A nineteenth embodiment includes methods according to any of the fifth and eighteenth embodiments, in which the controlled plant is at least one plant selected from the group consisting of: BRAPP, ECHCO, CYPIR, SCPJU, FIMMI, and CYPRO ; yet other embodiments include control plants from the genus consisting of: Urochloa, Brachiaría, Echinochloa, Cyperus, Schoenoplectus, and Fimbristylis.
[0024] A twentieth embodiment includes compositions according to the first or second embodiment, wherein (a) is the compound of Formula (I), or an agriculturally acceptable benzyl ester, and (b) is ha-losulfuron-methyl.
[0025] A twenty-first embodiment includes compositions according to the first or second embodiment, wherein (a) is the compound of Formula (I), or an agriculturally acceptable benzyl ester, and (b) is pyrazosulfuron-ethyl.
[0026] A twenty-second embodiment includes compositions according to the first or second embodiment, in which (a) is the compound of Formula (I), or an agriculturally acceptable benzyl ester, and (b) is esprocarb.
[0027] A twenty-third embodiment includes compositions according to any of the first to sixth, or twenty-twentieth-second embodiments, in which the composition is synergistic according to Colby's equation.
[0028] A twenty-fourth embodiment includes methods according to any of the seventh to nineteenth embodiments, in which the undesirable vegetation is immature.
[0029] A twenty-fifth embodiment includes methods according to any of the seventh to nineteenth embodiments, in which (a) and (b) are applied in water.
ou um sal agricolamente aceitável, ou éster do mesmo, e (b) halosulfu-ron-metila, pirazosulfuron-etila ou esprocarb. As composições podem também conter um adjuvante ou veículo agricolamente aceitável.[0030] Herbicidal compositions comprising a herbicidally effective amount of (a) a compound of Formula (I) are provided herein or an agriculturally acceptable salt, or ester thereof, and (b) halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb. The compositions can also contain an agriculturally acceptable adjuvant or vehicle.
[0031] Methods of controlling undesirable vegetation are also provided herein comprising applying (a) a compound of Formula (I), or an agriculturally acceptable ester, or salt thereof, and (b) halosulfuron-methyl, pyrazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt, or ester thereof. Detailed Description DEFINITIONS
[0032] As used herein, the compound of Formula (I) has the following structure:
[0033] The compound of Formula (I) can be identified by the name 4-amino-3-chloro-6- (4-chloro-2-fluor-3-methoxyphenyl) -5-fluorpyridine-2-carboxylic acid, and described in US Patent 7,314,849 (B2), which is incorporated herein by reference in its entirety. Exemplary uses of the Formula (I) compound include control of undesirable vegetation, including grass, broadleaf and grassy weeds, in multiple cultivation and non-cultivation situations.
[0034] As used here, sulfonylureas are used to control uncomfortable broad-leaf weeds, grass and grass.
[0035] Halosulfuron-methyl and pirazosulfuron-ethyl belong to a class of compounds referred to as sulfonylureas. Without being linked to any theory, sulfonylureas are believed to inhibit aceto-lactate synthase (ALS), an enzyme common to plants and microorganisms, but not found in animals.
[0036] Esprocarb belongs to a class of compounds referred to as VLCFA (very long chain fatty acid) and lipid synthesis which inhibit herbicides. Without being limited to any theory, this class of compounds is believed to inhibit very long chain fatty acid synthesis (VLCFA, fatty acids, for example,> C18) and lipid synthesis.
[0037] As used herein, halosulfuron-methyl is methyl 3-chloro-5- [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -1-methyl-1 / - / / - pyrazole-4-carboxylate, and has the following structure:
[0038] The compound is described in Tomlin, C., ed. A World Com-pendium The Pesticide Manual.15thed. Alton: BCPC Publications, 2009 (hereinafter "The Pesticide Manual, Fifteenth Edition, 2009."). Exemplary uses of halosulfuron-methyl include its use to control annual broadleaf weeds and annual / perennial grasses, for example, in corn, sugarcane, rice, sorghum, tree nuts and peat.
:[0039] As used herein, pirazosulfuron-ethyl is ethyl 5 - [[[[[[4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -1-methyl-1 / - / - pyrazole- 4 -carboxylate, and has the following structure :
[0040] The compound is described in The Pesticide Manual, Fifteenth Edition, 2009. Exemplary uses of pirazosulfuron-ethyl include its use to control annual and perennial broadleaf weeds and grasses, for example, in transplanted rice crops and wet seeding.
[0041] As used herein, esprocarb is S- (phenylmethyl) / V- (1,2-dimethylpropyl) -A / -ethylcarbamothioate, and has the following structure:
[0042] The compound is described in The Pesticide Manual, Fifteenth Edition, 2009. Exemplary uses of esprocarb include its use for pre and post-emergence control of annual weeds and Echinochloa spp, for example, in rice fields.
[0043] As used herein, herbicide means a compound, for example, an active ingredient, which kills, controls or otherwise adversely modifies the growth of plants.
[0044] As used herein, an amount of vegetation control, or herbicidally effective, is an amount of active ingredient that causes an adversely modifying effect to vegetation, for example, causing deviations from natural development, death, effecting regulation, causing desiccation, causing delay, and similar.
[0045] As used herein, control of undesirable vegetation means impediment, reduction, death, or, otherwise, adversely modifying the development of plants and vegetation. Methods for controlling undesirable vegetation by applying certain herbicide combinations or compositions are described herein. Application methods include, but are not limited to, applications to the vegetation or location of the same, for example, application to the area adjacent to the vegetation, as well as pre-emergence, post-emergence, leaf (widespread, directed, united, local, mechanical, on top, or rescue), and applications in water (immersed and submerged vegetation, diffused, local, mechanical, injected in water, diffused granular, granular location, oscillating bottle, or current spray), application methods via manual, backpack, machine, tractor, or aerial (airplane and helicopter).
[0046] As used herein, plants and vegetation include, but are not limited to, germinating seeds, emerging seedlings, plants emerging from vegetative propagules, immature vegetation, and established vegetation.
[0047] As used herein, agriculturally acceptable salts and esters refer to salts and esters that exhibit herbicidal activity, or that are or can be converted into plants, water, or soil, to the referenced herbicide. Exemplary agriculturally acceptable esters are those that are or can be hydrolyzed, oxidized, metabolized, or otherwise converted, for example, into plants, water, or soil, to the corresponding carboxylic acid which, depending on the pH, may be in the form dissociated or not dissociated.
Exemplary salts include those derived from alkali and alkaline earth metals and those derived from ammonia and amines. Exemplary cations include sodium, potassium, magnesium, and ammonium cations of the Formula: R1R2R3R4N + where R1, R2, R3 and R4 each independently represent hydrogen or C1-C12 alkyl, C3-C12 alkenyl, or C3-C12 alkynyl, each of which is optionally substituted by one or more hydroxy, C1-C4 alkoxy, C1-C4 alkylthio, or phenyl groups, provided that R1, R2, R3 and R4 are sterically compatible. In addition, any two of R1, R2, R3 and R4 together can represent an aliphatic difunctional portion containing one to twelve carbon atoms and up to two oxygen or sulfur atoms. Salts can be prepared by treatment with a metal hydroxide, such as sodium hydroxide, with an amine, such as ammonia, trimethylamine, diethanolamine, 2-methylthiopropylamine, bisalylamine, 2-butoxyethylamine, morpholine, cyclododecylamine, or benzylamine, or with a tetraalkylammonium hydroxide, such as tetramethylammonium hydroxide, or choline hydroxide.
Exemplary esters include those derived from C1-C12 alkyl, C3-C12 alkenyl, C3-C12 alkynyl or C7-C10 aryl-substituted alkyl alcohols, such as methyl ethyl alcohol, isopropyl alcohol, 1-butanol, 2-ethyl- hexanol, butoxyethanol, methoxypropanol, allyl allyl alcohol, propargyl alcohol, cyclohexanol or benzyl alcohols not substituted or substituted. Benzyl alcohols can be substituted with 1 to 3 substituents independently selected from halogen, C1-C4 alkyl or C1-C4 alkoxy. Esters can be prepared by coupling acids with alcohol using any number of suitable activating agents, such as those used for peptide couplings, such as dicyclohexylcarbodiimide (DCC) or carbonyl diimidazole (CDI); by reacting acids with alkylating agents, such as alkyl halides or alkyl sulfonates in the presence of a base, such as triethylamine or lithium carbonate; by reacting the corresponding acid chloride of an acid with an appropriate alcohol; by reacting the corresponding acid with an appropriate alcohol in the presence of an acid catalyst, or by transesterification. Compositions and Methods
ou um sal agricolamente aceitável ou éster do mesmo, e (b) halosulfu-ron-metila, pirazosulfuron-etila ou esprocarb, ou um sal agricolamente aceitável, éster, ácido carboxílico, ou sal de carboxilato dos mesmos.[0050] Herbicidal compositions comprising a herbicidally effective amount of (a) a compound of Formula (I) are provided herein or an agriculturally acceptable salt or ester thereof, and (b) halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt, ester, carboxylic acid, or carboxylate salt thereof.
[0051] Here are also provided methods of controlling undesirable vegetation comprising contacting the vegetation or the location thereof, that is, area adjacent to the plant, with, or application to the soil or water to prevent the emergence or growth of vegetation, of a herbicidally effective amount of the compound of Formula (I), or salt or ester thereof, and (b) halosulfuron-methyl, pyrazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt, ester, carboxylic acid, or carboxylate salt of themselves. In certain embodiments, the methods employ the compositions described herein.
[0052] Furthermore, in some embodiments, the combination of compound (I), or an agriculturally acceptable salt or ester thereof, and ha-losulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or a salt, ester, carboxylic acid, or carboxylate salt of the same, exhibits synergism, for example, the herbicidal active ingredients are more effective in combination than when applied individually. The Herbicide Handbook of the Weed Science Society of America, Ninth Edition, 2007, p. 429 notes that "‘ synergism ’[is] an interaction of two or more factors such that the effect when combined is greater than the effect predicted based on the response of each factor applied separately". In certain embodiments, the compositions exhibit synergy as determined by Colby's equation. Colby, S.R. 1967. Calculation of the synergistic and antagonistic response of herbicide combinations. Weeds 15: 20-22.
[0053] In certain embodiments of the compositions and methods described herein, the compound of Formula (I), i.e., carboxylic acid, is employed. In certain embodiments, a carboxylate salt of the compound of Formula (I) is employed. In certain embodiments, an aralkyl or alkyl ester is employed. In certain embodiments, a benzyl, substituted benzyl, or C1-4 alkyl, for example, n-butyl ester is employed. In certain embodiments, the benzyl ester is employed.
[0054] In some embodiments, the compound of Formula (I), or salt or ester thereof, and halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or agriculturally acceptable derivatives thereof, are formulated into a composition, mixed in a tank, applied simultaneously, or applied sequentially.
[0055] Herbicidal activity is exhibited by the compounds when they are applied directly to the plant, or to the location of the plant at any stage of growth. The observed effect depends on the species of plant to be controlled, the growth stage of the plant, the application parameters of dilution and spray droplet size, the particle size of solid components, the environmental conditions at the time of use, the specific compound used, the specific adjuvants and vehicles used, the type of soil, and the like, as well as the amount of chemicals applied. These and other factors can be adjusted to promote non-selective or selective herbicidal action. In some embodiments, the compositions described here are applied as a post-emergence application, pre-emergence application, application in water to flooded rice fields, or bodies of water (for example, ponds, lakes and streams), to undesirable vegetation relatively immature to achieve maximum weed control.
[0056] In some embodiments, the compositions and methods provided herein are used to control weeds in crops, including, but not limited to, direct sown rice, sown in water, and transplanted, cereals, wheat, barley, oats, rye, sorghum, maize / corn, sugar cane, sunflower, rapeseed, canola, sugar beet, soy, cotton, pineapple, pasture, grassland, pasture land, fallow, peat, vineyards and orchards, aquatic plantation crops, vegetables, water management industrial vegetation (IVM), and easements of passage (ROW).
[0057] In certain embodiments, the compositions and methods provided herein are used to control weeds in rice. In certain embodiments, rice is straight-sown rice, rice seeding in water, or transplanted rice.
[0058] The compositions and methods described herein can be used to control undesirable vegetation in glyphosate-tolerant inhibitor, 5-enolpyruvylshikimato-3-phosphate (EPSP) synthase, glufosinate-tolerant, glutamine-tolerant synthase inhibitor, dicamba tolerant, phenoxy auxin tolerant, pyridyloxy auxin tolerant, auxin tolerant, auxin tolerant transport inhibitor, aryloxyphenoxypropionate tolerant, cyclohexanedione tolerant, phenylpyrazoline tolerant, acetyl CoA carboxylase (ACCase) tolerant, tolerant imidazolinone, tolerant to sulfonylurea, tolerant to pyrimidinylthiobenzoate, tolerant to triazolopyrimidine-sulfonamide, tolerant to sulfonylaminocarbonyltriazolinone, tolerant inhibitor of acetolactate synthase (ALS), and a tolerant inhibitor of acid-hydroxy-4-hydroxy acid synthase () hydroxyphenylpyruvate dioxigenase (HPPD), phyteno desaturase tolerant inhibitor, bio tolerant inhibitor carotenoid synthesis, tolerant protoporphyrinogen oxidase (PPO) inhibitor, cellulose biosynthesis tolerant inhibitor, mitosis tolerant inhibitor, microtubule tolerant inhibitor, very long chain fatty acid tolerant inhibitor, tolerant fatty acid and lipid biosynthesis inhibitor, tolerant inhibitor of photosystem I, tolerant inhibitor of photosystem II, crops tolerant to triazine and crops tolerant to bromoxynil (such as, but not limited to, soy, cotton, canola / rapeseed, rice, cereals, corn, sorghum, sunflower, sugar beet, sugar cane, peat, etc.), for example, together with glyphosate, EPSP synthase inhibitors, glufosinate, glutamine synthase inhibitors, dicamba, auxin phenoxis, auxin pyridyloxis, synthetic auxins, transport inhibitors auxin, aryloxyphenoxypropionates, cyclohexanediones, phenylpyrazolines, ACCase inhibitors, imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazolopyrimidine sulfonamides, s ulfonylaminocarbonyltriazolinones, ALS or AHAS inhibitors, HPPD inhibitors, phytoene desaturase inhibitors, carotenoid biosynthesis inhibitors, PPO inhibitors, cellulose biosynthesis inhibitors, mitosis inhibitors, microtubule inhibitors, very long-chain fatty acid inhibitors fatty acid and lipid biosynthesis inhibitors, photosystem I inhibitors, photosystem II inhibitors, triazines and bromoxynil. The compositions and methods can be used to control undesirable vegetation in crops that have multiple or stacked treatments that confer tolerance to multiple chemicals and / or inhibitors of multiple modes of action. In some embodiments, the compound of Formula (I) or salt or ester thereof and complementary herbicide or salt or ester thereof, are used in combination with herbicides that are selective for the crop being treated, and that complement the spectrum of weeds controlled by these compounds at the application rate employed. In some embodiments, the compositions described herein and other complementary herbicides are applied at the same time, either as a combination formulation, tank mix, or sequentially.
[0059] The compositions and methods can be used to control undesirable vegetation in crops that have tolerance to agronomic stress (including, but not limited to, dry, cold, heat, salt, water, nutrient, fertility, pH), tolerance to pestilence (including, but not limited to, insects, fungi and pathogens), and cultivation improvement treatments (including, but not limited to, yield; protein, carbohydrate, or oil content; protein, carbohydrate, or oil composition; plant stature, and plant architecture).
[0060] The compositions and methods provided here are used to control undesirable vegetation. Undesirable vegetation includes, but is not limited to, undesirable vegetation that occurs in rice, cereals, wheat, barley, oats, rye, sorghum, corn / maize, sugar cane, sunflower, rapeseed, canola, sugar beet, soy, cotton , pineapple, grazing and grazing, pasture land, fallow, row crops (eg maize, soy, cotton, canola), peat, vineyards and orchards, ornamental species, aquatic plantation crops, plantation crops, vegetables or settlements without cultivation, (eg easements, industrial vegetation management).
[0061] In some embodiments, the methods provided here are used to control undesirable vegetation in rice. In certain embodiments, the undesirable vegetation is Brachiaria platyphylla (Groseb) Nash or Urochloa platyphylla (Nash) R.D. Webster (broadleaf grass, BRAPP), Digitaria sanguinalis (L.) Scop. (digitaria broad, DIGSA), Echinochloaspecies (ECHSS), Echinochloa crus-galli (L.) P. Beauv. (corral grass, ECHCG), Echinochloa crus-pavonis (Kunth) Schult, (gulf grass, ECHCV), Echinochloa colonum (L.) LINK (ECHCG wild rice), Echinochloa oryzoides (Ard.) Fritsch (chicken foot grass) premature, ECHOR), Echinochloa oryzicola (Vasinger) Vasinger (late crow's foot grass, ECHPH), Echinochloa phyllopogon (Stapf) Koso-Pol. (corral rice, ECHPH), Echinochloa polystachya (Kunth) Hitchc. (creeping river grass, ECHPO), Ischaemum rugosum Salisb. (saramolla grass, ISCRU), Leptochloa chinensis (L.) Nees (Chinese sprangletop, LEFCH), Leptochloa fascicularis (Lam.) Gray (bearded sprangletop, LEFFA), Leptochloa panicoides (Presl.) Hitchc. (Amazonian sprangletop, LEFPA), Oryza species (red and weak rice, ORYSS), Panicum dichotomiflorum (L.) Michx. (fallen grass, PANDI), Paspalum dilatatum Poir. (dallis grass, PASDI), Rottboellia cochinchinensis (Lour.) W.D. Clayton (itchy grass, ROOEX), Cyperusspecies (CYPSS), Cyperus difformis L. (small flat sedge flower, CYPDI), Cyperus dubius Rottb. (MAP-DU), Cyperus esculentus L. (yellow sedge, CYPES), Cyperus would L. (rice sedge, CYPIR), Cyperus rotundus L. (purple sedge, CYPRO), Cyperus serotinusRottb..ZC.B.Clarke ( marsh tide, CYPSE), Eleocharisspecies (ELOSS), Fimbristylis miliacea (L.) Vahl (globe reed, FIMMI), Schoenoplectusspecies (SCPSS), Schoenoplectus juncoides Roxb. (Japanese papyrus, SPCJU), Bolboschoenus maritimus (L.) Palia or Schoenoplectus maritimus L. Lye (agglomerated seagrass, SCPMA), Schoenoplectus mucronatus L. (rice field papyrus, SCPMU), Aeschynomene species, (jointvetch, AESSS ), Alternanthera philoxeroides (Mart.) Griseb. (alligator weed, ALRPH), Alisma plantago-aquatica L (common aquatic plant, ALSPA), Amaranthus species, (pig and amaranth amaranth, AMASS), Ammannia coccinea Rottb. (redstem, AMMCO), Commelina benghalensis L. (Bengal diurnal flower, COMBE), Eclipta alba (L.) Hassk. (false American daisy, ECLAL), Heteranthera limosa (SW.) Willd./Vahl (duck salad, HETLI), Heteranthera reniformis R. & P. (round leaf plant, HETRE), Ipomoea species (morning glory, IPOSS ), Ipomoea hederacea (L.) Jacq. (morning glory of ivy leaf, IPOHE), Lindernia dubia (L.) Pennell (false anagram, LIDDU), Ludwigiaspecies (LUDSS), Ludwigia linifolia Poir. (southeastern willow primrose, LUDLI), Ludwigia octovalvis (Jacq.) Raven (long fruit willow rhyme, LUDOC), Monochoria korsakowii Regei & Maack (monorail, MOOKA), Monochoria vaginalis (Burm. F.) C. Presl ex Kuhth , (monorail, MOOVA), Murdannia nudiflora (L.) Brenan (dove weed, MUDNU), Polygonum pensylvanicum L, (Pennsylvania weed, POLPY), Polygonum persicaria L. (leafy lady, POLPE), Polygonum hydropiperoides Michx . (POLHP, wild weed), Rotala indica (Willd.) Koehne (indigenous toothcup, ROTIN), Sagittariaspecies, (arrowhead, SAGSS), Sesbania exaltata (Raf.) Cory / Rydb. Ex Hill (sesbania hemp, SEBEX), or Sphe- noclea zeylanica Gaertn. (goose plant, SPDZE).
[0062] In some embodiments, the methods provided here are used to control undesirable vegetation in cereals. In certain embodiments, the undesirable vegetation is Alopecurus myo- suroides Huds. (black grass, ALOMY), Apera spica-venti (L.) Beauv. (wild grass, APESV), Avena fatua L. (wild oats, AVEFA), Bromus tectorum L. (woolly bromine, BROTE), Lolium multiflorum Lam. (Italian grass, LOLMU), Phalaris minorRetz. (small canary grass seed, PHAMI), Poa AnnuaL. (annual blue grass, POANN), Setaria pumila (Poir.) Roemer & J.A. Schultes (yellow foxtail, SETLU), Setaria viridis (L.) Beauv. (green fox tail, SETVI), Amaranthus retroflexus L. (red-rooted pig amaranth, AMARE), Brassica species (BRSSS), Chenopodium album L. (common lambsquarters, CHEAL), Cirsium arvense (L.) Scop, ( Canadian thistle, CIRAR), Galium aparine L. (weed in straw bale, GALAP), Kochia scoparia (L.) Schrad. (kochia, KCHSC), Lamium purpureum L. (purple nettle, LAMPU), Matricaria recutita L. (wild chamomile, MATCH), Matricaria matricarioides (Less.) Porter (pinion-shaped weed, MATMT), Papaver rhoeas L. (common poppy, PAPRH), Polygonum convolvulus L. (wild fallow wheat, POLCO), Salsola tragus L. (Russian thistle, SASKR), S / - napis species (SINSS), Sinapis arvensis L. (wild mustard, SI- NAR), Stellaria media (L.) Vill. (common chicken weed, STEME), Veronica persica Poir. (Persian veronica, VERPE), Viola arvensis Murr. (field violet, VIOAR), or Viola tricolor] -, (wild violet, VIOTR).
[0063] In some embodiments, the methods provided here are used to control undesirable vegetation in grazing and pasture, fallow, IVM and ROW. In certain embodiments, the undesirable vegetation is Ambrosia artemisiifolia L. (common tasna, AM-BEL), Cassia obtusifolia (sickle pod, CASOB), Centaurea maculosa auct. non Lam. (cornflower weed, CENMA), Cirsium arvense (L.) Scop. (Canadian thistle, CIRAR), Convolvulus arvensis L. (belted weed, CONAR), Daucus carota L. (wild carrot, DAUCA), Euphorbia esula L. (leafy spurge, EPHES), Lactuca serriola L./Torn . (prickly lettuce, LACSE), Plantago lanceo lata L. (deer antler plant, PLALA), Rumex obtusifolius L. (hardwood dock, RUMOB), Sida spinosa L. (guanxuma, SIDSP), Sinapis arvensis L. (wild mustard , SINAR), Sonchus arvensis L. (perennial seeded thistle, SONAR), Solidagospecies (goldenrod, SOOSS), Taraxacum officinale GH Weber ex Wiggers (dandelion, TAROF), Trifolium repens L. (white clover, TRFRE), or Urtica dioica L. (common nettle, URTDI).
[0064] In some embodiments, the methods provided here are used to control undesirable vegetation found in row crops, vineyards and orchards and perennial crops. In certain embodiments, the undesirable vegetation is Alopecurus myosuroides Huds. (black grass ,, ALOMY), Avena fatua L. (wild oats, AVE-FA), Brachiaria decumbens Stapf. or Urochloa decumbens (Stapf) R.D. Webster (grass from Suriname, BRADC), Brachiaria brizantha (Hochst. ex A. Rich.) Stapf. or Urochloa brizantha (Hochst. ex A. Rich.) RD (bearded grass, BRABR), Brachiaria platyphylla (Groseb.) Nash or Urochloa platyphylla (Nash) RD l / l / ebsfer (broadleaf brachiaria, BRAPP), Brachiaria plantaginea (Link) Hitchc. or Urochloa plantaginea (Link) R.D. Webster (alexander grass, BRAPL), Cenchrus echinatus L. (southern sandbur, CENEC), Digitaria horizontalisWilld. (Jamaican mattress grass, DIGHO), Digitaria insularis (L.) Mez ex Ekman (bitter grass, TRCIN), Digitaria sanguinalis (L.) Scop. (large mattress grass, DIGSA), Echinochloa crus-galli (L.) P. Beauv. (corral grass, ECHCG), Echinochloa coIonum (L.) Link (wild rice, ECHCO), Eleusine indica (L.) Gaertn. (goose grass, ELEIN), Lolium multiflo- rum Lam. (Italian rye grass, LOLMU), Panicum dichotomiflo- rum Michx. (fallen grass, PANDI), Panicum miliaceum L. (wild prose corn, PANMI), Setaria faberi Herrm. (giant fox tail, SETFA), Setaria viridis (L.) Beauv. (green fox tail, SETVI), Sorgus halepense (L.) Pers, (Johnson grass, SORHA), Sorgus bicolor (L.) Moench ssp. Arundinaceum (broken cane, SORVU), Cyperus esculentus L. (yellow nut, CYPES), Cyperus rotundus L. (purple nut, CYPRO), Abutilon theophrasti Medik. (velvety leaf, ABUTH), Amaranthus species (pig and amaranth amaranth, AMASS), Ambrosia artemisiifolia L. (common tasna, AMBEL), Ambrosia psilostachya DC. (western tasna, AMBPS), Ambrosia trifida L. (giant ragweed, AM-BTR), Anoda cristata (L.) Schlecht. (stimulated anoda, ANVCR), Aslepias syriaca L. (common milkweed, ASCSY), Bidens pilosa L. (hairy prick, BIDPI), Borreria species (BOISS), Borreria alata (Aubl.) DC. or Spermacoce alata Aubl. (broadleaf weed bud, BOILF), Spermacose latifolia (leafy weed bud, BOILF), Chenopodium album L. (common fedegosa, CHEAL), Cirsium arvense (L.) Scop, (Canada thistle, CIRAR) , Commelina benghalensis L. (tropical cornflower, COMBE), Datura stramonium L. (jimson weed, DATST), Daucus carota L. (wild carrot, DAUCA), Euphorbia heterophylla L. (good night wild, EPHHL), Euphorbia hirtaL. or Chamaesyce hirta (L.) Millsp. (garden spurge, EPHHI), Euphorbia dentata Michx. (toothed spurge, EPHDE), Erigeron bonariensis L. or Conyza bonariensis (L.) Cronq. (hairy pulicaria, ERI-BO), Erigeron canadensis L. or Conyza canadensis (L.) Cronq. (Canadian pulicaria, ERICA), Conyza sumatrensis (Retz.) E. H. Walker (exaggerated pulicaria, ERIFL), Helianthus annuus L. (common saffron, HE-LAN), Jacquemontia tamnifolia (L.) Griseb. (morning glory of small flower, IAQTA), Ipomoea hederacea (L.) Jacq. (morning glory ivy leaf, IPOHE), Ipomoea lacunosa L. (white morning glory, IPOLA), Lactuca serriola L./Torn. (prickly lettuce, LACSE), Portula oleracea L. (common purslane, POROL), Richardia species (pusley, RCHSS), Sida species (sida, SIDSS), Sida spinosa L. (prickly sida, SIDSP), Sinapis arvensis L (wild mustard, SINAR), Solanum ptychanthum Dunal (eastern black Moorish herb, SOLPT), Tridax procumbens L. (coated buds, TRQPR) or Xanthium strumarium L. (common thistle, XANST).
[0065] In some embodiments, the methods provided here are used to control undesirable vegetation in peat. In certain embodiments, the undesirable vegetation is Bellis perennisL. (English daisy, BELPE), Cyperus esculentus L. (yellow sedge, CYPES), Cyperusspecies (CYPSS), Digitaria sanguinalis (L.) Scop. (big mattress grass, DIGSA), Diodia virginiana L. (virginia weed bud, DIQVI), Euphorbia species (spurge, EPHSS), Gle- choma hederacea L. (ivy, GLEHE), Hydrocotyle umbellata L. ( dollar weed, HYDUM), Kyllinga species (kyllinga, KYLSS), Lumium amplexicaule L. (henbit, LAMAM), Murdannia nudiflora (L.) Breannan (pigeon weed, MUDNU), Oxalis species (wood of sorrel, OXASS), Plantago major L. (large leaf plant, PLAMA), Plantago lanceolata L. (deer antler / narrow leaf plant, PLALA), Phyllanthus urinaria L. (chamberbitter, PYLTE), Rumex obtusifolius L. (dock hardwood, RUMOB), Stachys floridana Shuttlew. (Florida beton, STAFL), Stellaria media (L.) Vill. (common chicken weed, STEME), Taraxacum officinale G.H. Weber ex Wiggers (dandelion, TAROF), Trifolium repens L. (white clover, TRFRE), or Viola species (wild violet VIOSS).
[0066] In some embodiments, the compositions and methods provided here are used to control undesirable vegetation consisting of grass, grass weeds and broadleaf. In certain embodiments, the compositions and methods provided herein are used to control undesirable vegetation including Brachiariaou Urochloa, Cyperus, Digitaria, Echinochloa, Fimbristylis, Ipomoea, Leptochloa and Schoenoplectus.
[0067] The compounds of Formula I, or agriculturally acceptable salt, or ester thereof, can be used to control weed resistant or herbicide-tolerant. The methods employing the combination of a Formula I compound, or an agriculturally acceptable salt, or ester thereof, and the compositions described herein, may also be employed for herbicide-resistant or herbicide-tolerant weed control. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes resistant or tolerant to acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitors, (eg, imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazolopyrimidine-sulfonides, sulfonylamino-carbonyltriazolinones), photosystem II inhibitors, (for example, phenylcarbamates, pyridazinones, triazines, triazinones, uracis, amides, ureas, benzothiadiazinones, nitriles, phenylpyridazine), acetyl Co-carboxylase (ACC) inhibitors, for example , cyclohexanediones, phenylpyrazolines), synthetic auxins (eg, benzoic acids, phenoxycarboxylic acids, pyridine carboxylic acids, quinoline carboxylic acids), auxin transport inhibitors (eg phthalates, semicarbazones), photosystem inhibitors I (eg bipuridyls), 5-enolpyruvylshikimato-3-phosphate (EPSP) synthase inhibitors (eg lo, glyphosate), glutamine synthetase inhibitors (eg, glufosinate, bialafos), microtubule assembly inhibitors (eg, benzamides, benzoic acids, dinitroanilines, phosphoramidates, pyridines), mitosis inhibitors (eg carbamates) , very long chain fatty acid (VLCFA) inhibitors (eg acetamides, chloroacetamides, oxyacetamides, tetrazolines), fatty acid and lipid synthesis inhibitors (eg phosphodithioates, thiocarbamates, benzofurans, chlorocarbonic acids), inhibitors protoporphyrinogen oxidase (PPO) (for example, diphenylethers, N-phenylphthalimides, oxadiazoles, oxazolidinediones, phenylpyrazoles, pyrimidionines, thiadiazoles, triazolinones), carotenoid biosynthesis inhibitors (eg, clomazone, amitrole, amitrole, amitrole, amitrole , phytoene desaturase (PDS) inhibitors (eg, amides, anilidex, furanones, phenoxybutan-amides, pyridiazinones, pyridines), 4-hydroxyphenyl-pyruvate-dioxigenase (HPPD) inhibitors (by callistemones, isoxazoles, pyrazoles, tricetones), cellulose biosynthesis inhibitors (for example, nitriles, benzamides, quinclorac, triazolocarboxamides), herbicides with multiple modes of action such as quinclorac, and unclassified herbicides such as arylaminopropionic acids, diphenyl - zoquat, endotal, and organoarsenic. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes with resistance or tolerance to multiple herbicides, biotypes with resistance or tolerance to multiple chemical classes, biotypes with resistance or tolerance to multiple herbicide modes of action, and biotypes with mechanisms of multiple resistance or tolerance (for example, resistance to the target site or metabolic resistance).
[0068] In some embodiments, the combination of compound (I), or agriculturally acceptable ester, or salt thereof, and halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, or an agriculturally acceptable salt, or ester thereof, is used to control of Brachiaria platyphylla (Griseb.) Nash (broadleaf brachiaria, BRAPP), Cyperus would L. (rice nutsedge, CYPIR), Cyperus rotundus L. (purple nutsedge, CYPRO), Digitaria sanguinalis (L.) Scop. (large mattress grass, DIGSA), Echinochloa colona (L.) Link (wild rice, ECHCG), Echinochloa oryzoides (Ard.) Fritsch (premature chicken leg grass, ECHOR), Echinochloa crus-galli (L.) Beauv. (corral grass, ECHCG), Fimbristylis miliacea (L.) Vahl (rush of the globe, FIMMI), Ipomoea hedacea Jacq. (ivy leaf morning glory, IPOHE), Leptochloa chinensis (L.) Nees (Chinese sprangletop, LEECH), Schoenoplectus juncoides (Roxb.) Palia (Japanese papyrus, SCPJU) and Schoenoplectus maritimus (L.) Lye (agglomerated seagrass , SCPMA).
[0069] In some embodiments, an agriculturally acceptable ester or salt of compound (I) is employed. In certain embodiments, an agriculturally acceptable ester is employed. In certain embodiments, the ester is a C1-4 alkyl ester. In certain embodiments, the ester is an n-butyl ester. In certain embodiments, the ester is a benzyl ester. In certain embodiments, compound (I), which is a carboxylic acid, is employed.
[0070] In some embodiments, an agriculturally acceptable ester or salt of halosulfuron-methyl, pirazosulfuron-ethyl or esprocarb, is employed in the methods or compositions described herein.
[0071] In certain embodiments of the compositions and methods described herein, the compound of Formula (I), or salt or ester thereof, is used in combination with halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt of themselves. With respect to the compositions, in some embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof , is within the range from about 1:70 to about 214: 1. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, is within the range from from 1: 8 to about 20: 1. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, is within the range from 5: 1 to about 1: 8. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to halosulfuron-methyl, or salt, esters, carboxylic acid, or carboxylate salt thereof, is within the range from 2.4: 1 to about 1: 3.7. In certain embodiments, the composition comprises the compound of Formula I and halosulfuron-methyl. In certain embodiments, the composition comprises the compound of Formula I and halosulfuron-methyl, in which the weight ratio of the compound of Formula I to halosulfuron-methyl is from about 1: 8 to about 5: 1. In certain embodiments, the composition comprises the compound of Formula I and halosulfuron-methyl, in which the weight ratio of the compound of Formula I to halosulfuron-methyl is from about 1: 4 to about 2.4: 1. In certain embodiments, the composition comprises the benzyl ester of the compound of Formula I and halosulfuron-methyl. In certain embodiments, the composition comprises the benzyl ester of the compound of Formula I and halosulfuron-methyl, in which the weight ratio of the benzyl ester of the compound of Formula I to halosulfuron-methyl is from about 4: 1 to about 1: 8. In certain embodiments, the composition comprises the benzyl ester of the compound of Formula I and halosulfuron-methyl, in which the weight ratio of the benzyl ester of the compound of Formula I to halosulfuron-methyl is from about 2: 1 to about 1: 3.7. With respect to the methods, in certain embodiments, the methods comprise contacting the undesirable vegetation, or location thereof, or application to soil or water to prevent the emergence or growth of vegetation, with a composition described herein. In some embodiments, the composition is applied at an application rate from about 3.4 grams of active ingredient per hectare (g ai / ha) to about 440 g ai / ha, based on the total amount of active ingredients in the composition. In certain embodiments, the composition is applied at an application rate from about 9 grams of active ingredients per hectare (g ai / ha), to about 120 g ai / ha, based on the total amount of active ingredients in the composition. In some embodiments, the methods comprise contacting undesirable or local vegetation, or application to soil or water to prevent the emergence or growth of vegetation with a compound of Formula (I), or salt, or ester thereof, and halosulfuron- methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, for example, sequentially or simultaneously. In some embodiments, halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, is applied at a rate from about 1.4 g ai / ha to about 140 g ai / ha, and the compound of Formula (I), of salt, or ester thereof, is applied at a rate from about 2 g ae / ha to about 300 g ae / ha. In some embodiments, halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, is applied at a rate from about 4 g ai / ha to about 40 g ai / ha, and the compound of Formula (I) of salt, or ester thereof, is applied at a rate from about 4 g ae / ha to about 85 g ae / ha. In certain embodiments, the methods use the compound of Formula (I), or its benzyl or n-butyl ester, and halosulfuron-methyl. In one embodiment, the compound of Formula (I), or its benzyl, or n-butyl ester, is applied at a rate from about 4 to about 85 g ae / ha, and the halosulfuron methyl is applied at a rate from about 4 to about 35 g ai / ha. In certain embodiments, the methods and compositions using the compound of Formula (I), or salt, or ester thereof, in combination with halosulfuron-methyl, or salt, ester, carboxylic acid, or carboxylate salt thereof, are used to control BRAPP, DIGSA, LEFCH, ECHOR, ECHCG, CYPRO or SCPMA,
[0072] In certain embodiments of the compositions and methods described herein, the compound of Formula (I), or salt, or ester thereof, is used in combination with pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof. In some embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is within the range from about 1:60 to about 600: 1. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to pi-razosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is within the range from 1:27 to about 168: 1. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is within the range from from 4: 1 to about 1:28. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is within the range from from 2: 1 to about 1:14. With respect to the methods, in certain embodiments, the methods comprise contacting the undesirable vegetation, or location thereof, or application to soil or water to prevent the emergence or growth of vegetation, of a composition described herein. In some embodiments, the composition is applied at an application rate from about 2.5 grams of active ingredient per hectare (g ai / ha) to about 420 g ai / ha, based on the total amount of active ingredients in the composition. In certain embodiments, the composition is applied at an application rate from about 5 grams of active ingredients per hectare (g ai / ha) to about 204 g ai / ha based on the total amount of active ingredients in the composition. In some embodiments, the methods comprise contacting undesirable vegetation, or location thereof, or application to soil or water to prevent the emergence or growth of vegetation with a compound of Formula (I), or salt, or ester thereof, and pirazosulfuron -ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, for example, sequentially or simultaneously. In some embodiments, pyrazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is applied at a rate from about 0.5 g ai / ha to about 120 g ai / ha, and the compound of Formula (I) of salt, or ester thereof, is applied at a rate from about 2 g ae / ha to about 300 g ae / ha. In some embodiments, pyrazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is applied at a rate from about 2 g ai / ha to about 250 g ai / ha, and the compound of Formula (I) of salt or ester thereof, is applied at a rate from about 2 g of acid equivalent per hectare (g ae / ha) to about 160 g ae / ha. In some embodiments, pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, is applied at a rate from about 5 g ai / ha to about 120 g ai / ha, and the compound of Formula (I) of salt, or ester thereof, is applied at a rate from about 4 g of acid equivalent per hectare (g ae / ha) to about 85 g ae / ha. In certain embodiments, the methods use the compound of Formula (I) or its benzyl or n-butyl ester and pyrazosulfuron-ethyl. In one embodiment, the methods use the compound of Formula (I) and pirazosulfuron-ethyl, in which the compound of Formula (I) is applied at a rate from about 4 g of acid equivalent per hectare (g ae / ha ) at about 85 g ae / ha, and pyrazosulfuron-ethyl is applied at a rate from about 5 g ai / ha to about 120 g ai / ha. In one embodiment, the methods use the benzyl ester of the compound of Formula (I) and pirazosulfuron-ethyl, in which the benzyl ester of the compound of Formula (I) is applied at a rate from about 4 g of acid equivalent per hectare (g ae / ha) at about 35 g ae / ha, and the pirazosulfuron-ethyl is applied at a rate from about 5 g ai / ha to about 120 g ai / ha. In one embodiment, the methods use the n-butyl ester of the compound of Formula (I) and pirazosulfuron-ethyl, in which the n-butyl ester of the compound of Formula (I) is applied at a rate from about 18 g of acid equivalent per hectare (g ae / ha) to about 50 g ae / ha, and pirazosulfuron-ethyl is applied at a rate from about 7.5 g ai / ha to about 120 g ai / ha . In certain embodiments, methods and compositions using the compound of Formula (I), or salt, or ester thereof, in combination with pirazosulfuron-ethyl, or salt, carboxylic acid, carboxylate salt, or ester thereof, are used to control of DIGSA, BRAPP, ECHOR, SCPMA, ECHCG, CYPDI or LEFCH.
[0073] In certain embodiments of the compositions and methods described herein, the compound of Formula (I), or salt, or ester thereof, is used in combination with esprocarb, or salt thereof. With respect to the compositions, in some embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to esprocarb, or salt thereof, is within the range from about 1: 500 to about 6: 1. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to esprocarb, or salt thereof, is within the range of 1:48 to about 1: 3. In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to esprocarb, or salt thereof, is within the range from about 1: 3 to about 1: 100 . In certain embodiments, the weight ratio of the compound of Formula (I), or salt, or ester thereof, to esprocarb, or salt thereof, is within the range from about 1: 6 to about 1 : 48. In certain embodiments, the compositions provided herein comprise the compound of Formula (I), or its benzyl ester and esprocarb. In one embodiment, the composition comprises the compound of Formula (I) and esprocarb, in which the weight ratio of the compound of Formula (I) and esprocarb is about 1: 6 to about 1:24. In one embodiment, the composition comprises the benzyl ester of the compound of Formula (I) and esprocarb, in which the weight ratio of the benzyl ester of the compound of Formula (I) and esprocarb is about 1: 3 to about 1 : 48. With respect to the methods, in certain embodiments, the methods comprise contacting the undesirable vegetation, or location thereof, or application to soil or water to prevent the emergence or growth of vegetation, of a composition described herein. In some embodiments, the composition is applied at an application rate from about 55 grams of active ingredients per hectare (g ai / ha) to about 1300 g ai / ha, based on the total amount of active ingredients in the composition . In certain embodiments, the composition is applied at an application rate from about 57 grams of active ingredients per hectare (g ai / ha) to about 230 g ai / ha based on the total amount of ingredients. active in the composition. In some embodiments, the methods comprise contacting the undesirable vegetation, or location thereof, or application to soil or water to prevent the emergence or growth of vegetation with a compound of Formula (I), or salt, or ester thereof, and sprocarb , or salt thereof, for example, sequentially or simultaneously. In some embodiments, esprocarb, or salt thereof, is applied at a rate from about 53 g ai / ha to about 1000 g ai / ha, and the compound of Formula (I) of salt, or ester of the themselves, it is applied at a rate from about 2 g ae / ha to about 300 g ae / ha. In some embodiments, esprocarb, or salt thereof, is applied at a rate from about 25 g ai / ha to about 450 g ai / h, and the compound of Formula (I) of salt, or ester of the themselves, it is applied at a rate from about 2 g of acid equivalent per hectare (g ae / ha) to about 40 g ae / ha. In some embodiments, esprocarb, or salt thereof, is applied at a rate from about 50 g ai / ha to about 220 g ai / ha, and the compound of Formula (I) of salt, or ester of the themselves, it is applied at a rate from about 4 g of acid equivalent per hectare (g ae / ha) to about 20 g ae / ha. In certain embodiments, the methods use the compound of Formula (I), or its benzyl, or ester and esprocarb. In one embodiment, the methods use the compound of Formula (I) and es-procarb, in which the compound of Formula (I) is applied at a rate from about 4 g of acid equivalent per hectare (g ae / ha ) at about 20 g ae / ha, and sprocarb is applied at a rate from about 50 g ai / ha to about 210 g ai / ha. In one embodiment, the methods use the benzyl ester of the compound of Formula (I) and esprocarb, in which the benzyl ester of the compound of Formula (I) is applied at a rate from about 4 g of acid equivalent per hectare ( g ae / ha) to about 10 g ae / ha, and esprocarb is applied at a rate from about 50 g ai / ha to about 220 g ai / ha. In certain embodiments, methods and compositions that use the compound of Formula (I), or salt, or ester thereof, in combination with esprocarb thereof, are used to control BRAPP, ECHCO, CYPIR, SCPJU, CYPRO, or FIMMI .
[0074] The components of the mixtures described here can be applied either separately, or as part of a multipart herbicidal system.
[0075] The mixtures described here can be applied in conjunction with one or more other herbicides to control a wider variety of undesirable vegetation. When in conjunction with other herbicides, the composition can be formulated with the other herbicide or herbicides, mixed in tank with the other herbicide or herbicides, or applied sequentially with the other herbicide or herbicides. Some of the herbicides that can be used in conjunction with the compositions and methods described herein include, but are not limited to: 4-CPA; 4-CPB; 4-CPP; 2,4-D; 2,4-D choline salt, 2,4-D esters and amines, 2,4-DB; 3,4-DA; 3,4-DB; 2,4-DEB; 2,4-DEP; 3,4-DP; 2,3,6-TBA; 2,4,5-T; 2,4,5-TB; acetochlor, acifluorfen, aclonifen, acrolein, alachlor, alidochlor, aloxidim, allyl alcohol, alorac, ametridione, amtrin, amibuzin, amicarbazone, amidosulfuron, aminocyclopyraclor, aminopyralid, amiprofos-methyl, amitrole, amitrole, amitrole, amitrole , anisuron, asulam, atraton, atrazine, azafenidin, azimsulfuron, aziprotein, barban, BCPC, beflubutamid, benazolin, bencarbazone, benfluralin, benfuresate, bensulfuron-methyl, bensulide, bentiocarf, benzentobenzamide, benzentamide, benzentamide , benzophene, benzofluor, benzoylprop, benzthiazuron, bialafos, bicyclopyrone, bi-phenox, bilanafos, bispiribac-sodium, borax, bromacil, bromobonyl, bromo-butide, bromophenoxin, bromoxynil, brompirazon, butachloram, butachlor, butachlor, butachlor, butachlor, butachlor , butiuron, butralin, butroxidim, buturon, butylate, cacodylic acid, cafenstrole, calcium chlorate, calcium cyanamide, cambendichlor, carbasulam, carbetamide, chlorprocarb carboxazole, ethyl carfentrazone, CDEA, CEPC, clomethoxyfen, chloramben, chloranocril, chlorazifop, chlorazine, chlorobromuron, chloroburam, chloreturon, chlorfenac, chlorfenprop, chlorflurazole, chlorflurenol, chloridazon, chlorimuron, chlorornorphen, chloropon, chlorotoluron, chloroxuron, chloroxuron, chloroxuron, chloroxuron, chloroxuron cinidon-ethyl, cinmetilin, cinosulfuron, cisanilide, cletodim, cliodinato, clodinafop-propargila, clofop, clomazone, dome-prop, cloprop, cloproxidim, clopyralid, chloransulam-methyl, CMA, copper sulfate, CPMF, CPPC, cumiluron, cyanatrin, cyanozine, cyclate, cyclopyrimorate, cyclosulfamuron, cyclooxidim, cycluron, cyhalofop-butyl, cyperquat, cyprazine, cyprazole, cipromid, daimuron, dalapon, dazomet, delaclor, desmedicam, dimedicam, desmedicam, desmedicam, dimedin dichlobenyl, dichloralurea, dichlormate, dichlorprop, dichlorprop-P, diclofopmethyl, diclosulam, dietamquat, diethyl, diphenopenten, diphenoxuron, diphenzoquat, diflufenican, diflufenzopyr, dimefuron, dimepiperate, dimepiperate, dimepiperate tametrin, dimetenamid, dimetenamid-P, dimexane, dimidazon, dinitramine, dinofenate, dinoprop, dinosam, dinoseb, dinoterb, diphenamid, dipropetrin, diquat, disul, dithiopir, diuron, DMPA, DNOC, DSMA, EBEP, eglinazine endotal, epronaz, EPTC, erbon, etalfluralin, etbenzamide, etametsulfuron, etidimuron, etiolate, etobenzamid, eto-benzamid, etofumesate, ethoxyfen, ethoxysulfuron, etinofen, etnipromid, etobenzanid, ethoxy, phenoxy, phenoxyphenol fenoxaprop-P-ethyl + isoxadifen-ethyl, fenoxasulfone, fenteracol, fentiaprop, fentrazamid, fenuron, ferrous sulfate, flamprop, flamprop-M, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, fluazolate, flucuron, flucon , flufenacet, flufenican, flufenpir-ethyl, flumetsulam, flumezin, flumiclorac-pentila, flumioxazin, flumipropin, fluometuron, flúordifen, flúorglicofen, flúormidina, flúornitrofen, fluotiu-flon, flupo, fluoro, fluoro, fluoro, fluoro, fluoro, fluoro na, fluroxypyr, fluroxypyr-meptila, flurtamone, flutiacet, fomesafen, foramsulfuron, foramsulfuron, fumiclorac, furiloxifen, glufosinate, glufosin-to-ammonia, glufosinate-P-ammonia, glyphosate, halauxifen, halo-halo, methyl, haloxifop-P-methyl, hexachloroacetone, hexaflurate, hexazinone, imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazosulfuron, imazetapyr, indanofan, indaziflam, iodobonyl, iodine-iodine, iodine-iodine, iodo ipazine, ipfencarbazone, iprimidam, isocarbamid, isocyl, isometiozin, isonoruron, isopolinate, isopropalin, isoproturon, isouron, isoxaben, isoxaclortole, isoxaflutole, isoxapirifop, karbutilate, amofox, PA, isotonic, lactofac -tioethyl, MCPB, mecoprop, mecoprop-P, medinoterb, me-fenacet, mefluidide, mesoprazine, mesosulfuron, mesotrione, metam, metamifop, metamitron, metazachlor, metazosulfuron, metflurazon, metabenztiazuron, m etalpropalin, metazol, metiobencarb, metiozolin, meiuron, metometon, metoprotrin, methyl bromide, methyl isothiocyanate, methyldimron, metobenzuron, metobromuron, metolachlor, metosulam, metoxuron, metiburin, metulfuron, metsulfuron, molsulfuron, , monochloroacetic acid, monolinuron, monuron, morfamquat, MSMA, naproanilide, napropamide, naptalam, neburon, nicosulfuron, nipiraclofen, nitralin, nitrofen, nitrofluorfen, norflurazon, noruron, OCH, orbencarizor, orbencorizor, orbencor, orb oxadiazon, oxapirazon, oxasulfuron, oxaziclomefone, oxifluorfen, paraflufen-ethyl, parafluron, paraquat, pebulate, peplonic acid, pendimetalin, penoxsulam, pentachlorophenol, pentanochlor, pentoxazone, perfluidone, phenluidone, phenluamide, phenoxyphenamide, phenluamide, phenluamide, , phenylmercury acetate, picloram, picoline-phen, pinoxaden, piperophos, potassium arsenite, potassium azide, potassium cyanate, pretilachlor, primisulfuron-m ethyl, prociazine, prodiamine, profluazole, profluralin, profoxidim, proglinazine, prohexadione-calcium, prometon, prometrin, pronamide, propachlor, propanyl, propaquizafop, propazine, profam, propisochlor, propoxycarbazone, propirisulfuron, propiraminulfonate, prospraminate prosulfuron, proxan, prinaclor, piñon, piraclonil, piraflufen-ethyl, pirasulfotole, pyrazogyl, pyrazolinate, pyrazoxifen, pyribenzoxim, pyributicarb, pyrichloride, pyridate, pyrifta-lid, pyriminobac, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan, pyrimoxysulfan. lam, quinclorac, quinmerac, quinoclamine, quinonamid, quizalofop, quizalofop-P-ethyl, rodetanil, rimsulfuron, saflufenacil, S-metolachlor, sebutilazine, secbumeton, setoxidim, siduron, simazine, simeton, simetrin, simetrin sodium, sodium azide, sodium chlorate, sulcotrione, sulphate, sulfentrazone, sulfometuron, sulfosate, sulfosulfuron, sulfuric acid, sulglicapin, swep, SYN-523, TCA, tebutam, tebutiuron, tefuriltrine, tembotrio na, tepraloxidim, terbacil, terbucarb, terbuclor, terbume- ton, terbutilazine, terbutrin, tetrafluron, tenilchlor, tiazafluron, tiazopir, tidiazimin, tidiazuron, tiencarbazone-methyl, tifensulfuron, tifensulfuron, tifensulfuron, tifensulfuron, tifensulfuron, tifensulfuron, tifensulfuron, tifensulfuron triafonone, tri-alate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, tricamba, triclopir choline salt, triclopyr esters and salts, tridiphane, tretazine, trifloxysulfuron, trifluralin, triflusulfurine, trifopyrine, trifopyrine, trifopyrine trimeturon, tripropindan, tritac tritosulfuron, vernolate, xylachlor and salts, esters, optionally, active isomers, and mixtures thereof.
[0076] The compositions and methods described herein, may additionally be used in conjunction with glyphosate, 5-enolpyruvylshikimato-3-phosphate (EPSP) synthase, glufosinate inhibitors, glutamine synthetase inhibitors, dicamba, phenoxis auxins, pyridyloxy auxins, synthetic auxins, auxin transport inhibitors, aryloxyphenoxypropionates, cyclohexanediones, phenylpyrazolines, acetyl CoA carboxylase (ACCase) inhibitors, imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazolopyrimidine-sulfonylsulphonylsulfonylsulphonylsulfonates ) or acetohydroxy acid synthase (AHAS), 4-hydroxyphenylpyruvate dioxigenase (HPPD) inhibitors, phytoene desaturase inhibitors, carotenoid biosynthesis inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, cellulose biosynthesis inhibitors, cellulose inhibitors mitosis, microtubule inhibitors, very long chain fatty acid inhibitors, acid biosynthesis inhibitors of fatty and lipid, photosystem I inhibitors, photosystem II inhibitors, triazines, and tolerant to bromoxynil in glyphosate, tolerant to EPSP synthase inhibitor, tolerant to glufosinate, tolerant to glutamine synthase inhibitor, tolerant to dicamba, tolerant to phenoxy auxin , tolerant to pyridyloxy auxin, tolerant to auxin, tolerant to auxin transport inhibitor, tolerant to aryloxyphenoxypropionate, tolerant to cyclohexanedione, tolerant to phenylpyrazoline, tolerant to ACCase, tolerant to imidazolinone, tolerant to sulfonylurea, tolerant to pyrimidinylbiotide triazolopyrimidine-sulfonamide, tolerant to sulfonylaminocarbonyltriazolinone, tolerant to ALS or AHAS, tolerant to HPPD, tolerant to phytene desaturase inhibitor, tolerant to carotenoid biosynthesis inhibitor, tolerant to PPO, tolerant to cellulose biosynthesis inhibitor, tolerant to cellulose biosynthesis inhibitor, tolerant to cellulose biosynthesis inhibitor , tolerant to microtubule inhibitor, tolerant to chain fatty acid inhibitor the very long, tolerant to fatty acid and lipid biosynthesis inhibitor, tolerant to photosystem inhibitor I, tolerant to photosystem inhibitor II, tolerant to triazine, tolerant to bromoxynil, and crops that have multiple or stacked treatments that confer tolerance to chemicals multiple and / or multiple modes of action, via single and / or multiple resistance mechanisms. In some embodiments, the compound of Formula (I), or salt, or ester thereof, and complementary herbicide, or salt, or ester thereof, are used in combination with herbicides that are selective for the crop being treated, and that complement the spectrum of weeds controlled by these compounds at the application rate employed. In some embodiments, the compositions described herein and other complementary herbicides are applied at the same time, either as a combination formulation, as a tank mix, or as a sequential application.
[0077] In some embodiments, the compositions described herein are used in combination with one or more herbicide protection agents, such as AD-67 (MON 4660), benoxacor, bentio carb, brassinolide, cloquintocet (mexila), ciometrinyl, daimuron, di-clormid, dicyclonon, dimepiperate, disulfoton, fenclorazol-ethyl, fenclo-rim, flurazole, fluxofenim, furilazol, harpin proteins, isoxadifen-ethyl, jie-caowan, jiecaoxy, mefenpir-diethyl, napenate, mepenate, napenate (napenate) , oxabetrinyl, R29148 and A / -phenyl-sulfonylbenzoic acid amides, to intensify their selectivity. In some embodiments, protective agents are used in rice, cereal, corn, or loads of corn. In some embodiments, the protective agent is cloquintocet, or an ester, or salt thereof. In certain embodiments, cloquintocet is used to antagonize harmful effects of the compositions on rice and cereals. In some embodiments, the protective agent is cloquintocet (mexila).
[0078] In some embodiments, the compositions described herein are employed in combination with one or more plant growth regulators, such as 2,3,5-triiodediobenzoic acid, IAA, IBA, naphthalene acetamide, α-naphthalene acetic acids, benzyladenine , 4-hydroxyphenethyl alcohol, kinetin, zeatin, endotal, etefon, pentachlorophenol, tidiazuron, tribufos, aviglycine, maleic hydrazide, gibberellins, gibberellic acid, abscisic acid, ancimidol, phosphine, glyphosine, isopyrimol, 2, isotirimol acid, jasmine , 3,5-triiodiodobenzoic, morphactins, dichlorflurenol, flurprimidol, mefluidide, paclobutrazol, tetciclacis, single-nazole, brassinolide, brassinolide-ethyl, cycloheximide, ethylene, metasul-focarb, pro-hexadione, triapentone and triapentone.
[0079] In some embodiments, plant growth regulators are used in one or more crops or configurations, such as rice, cereal crops, corn, broadleaf crops, rapeseed / canola, peat, pineapple, sugar cane, sunflower, pastures, prairies, pasture land, fallow, vineyards and orchards, plantation crops, vegetables, and non-cultivation configurations (ornamental). In some embodiments, the plant growth regulator is mixed with the compound of Formula (I), or mixed with the compound of Formula (I) and halosulfuron-methyl, pirazosulfuron-ethyl, or esprocarb, to cause a preferential effect advantageous in plants.
[0080] In some embodiments, the compositions provided herein additionally comprise at least one agriculturally acceptable adjuvant or vehicle. Suitable adjuvants or vehicles should not be phytotoxic to valuable crops, particularly in concentrations used in the application of compositions for selective weed control in the presence of crops, and should not react chemically with herbicidal components, or other composition ingredients. Such mixtures can be designed for application directly to weeds or locations there, or they can be concentrated or formulations that are normally diluted with additional vehicles and adjuvants before application. They can be solids, such as, for example, powders, granules, water-dispersible granules, or wetting powders, or liquids, such as, for example, emulsifiable concentrates, solutions, emulsions or suspensions. They can also be provided as a premix, or tank mixed.
[0081] Suitable agricultural adjuvants and vehicles include, but are not limited to, cultivated oil concentrate; nonylphenol ethoxylate; benzylcocoalkylimethyl quaternary ammonium salt; mixture of petroleum hydrocarbon, alkyl esters, organic acid, and anionic surfactant; C9-C11 alkyl polyglycoside; phosphated ethoxylate alcohol; natural primary alcohol (C12-C16) ethoxylate; di-sec-butylphenol EO-PO block copolymer; polysiloxane-methyl cap; nonylphenol ethoxylate + urea ammonium nitrate; emulsified methylated seed oil; tri-decyl alcohol (synthetic) ethoxylate (8EO); tallow ethoxylate amine (15 EO); PEG (400) dioleate-99.
[0082] Liquid vehicles that can be used include water and organic solvents. Organic solvents include, but are not limited to, petroleum or hydrocarbon fractions, such as mineral oil, aromatic solvents, paraffinic oils, and the like; vegetable oils, such as soybean oil, rapeseed oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, linseed oil, oil palm oil, amen-doim oil, sunflower oil, sesame oil, tung oil, and the like; esters of the above vegetable oils; esters of monoalcohols or dihydric, trihydric polyalcohols, or other lower polyalcohols (containing 4-6 hydroxy), such as 2-ethyl hexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, dioctyl succinate, di-butyl adipate, dioctyl phthalate, and the like; esters of mono-, di- and poly-carboxylic acids, and the like. Specific organic solvents include, but are not limited to, toluene, xylene, petroleum naphtha, culture oil, acetone, methyl ethyl ketone, cyclohexanone, trichlorethylene, perchlorethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol monomethyl ether, and diethylene glycol monomethyl ether, ethyl alcohol, ethyl alcohol, isopropyl alcohol, amyl alcohol, ethylene glycol, propylene glycol, glycerin, A / -methyl-2-pyrrolidinone, / V, / V-di methyl alkylamides, dimethyl sulfoxide, liquid fertilizers, and the like. In certain embodiments, water is the vehicle for diluting concentrates.
[0083] Suitable solid vehicles include, but are not limited to, talc, pyrophyllite clay, silica, attapulgus clay, kaolin clay, kieselguhr, chalk, diatomaceous earth, limestone, calcium carbonate, bentonite clay, earth Fuller, cottonseed husks, wheat flour, soy flour, pumice stone, sawdust, nutshell flour, lignin, cellulose, and the like.
[0084] In some embodiments, the compositions described herein additionally comprise one or more surface active agents. In some embodiments, such surface active agents are employed in both solid and liquid compositions, and, in certain embodiments, those designed to be diluted with a vehicle before application. Surface active agents can be anionic, cationic or non-ionic in character, and can be used as emulsifying agents, wetting agents, suspending agents, or for other purposes. Surfactants that can also be used in the present formulations are described, inter alia, in "McCutcheon's Detergents and Emulsifiers Annual," MC Publishing Corp., Ridgewood, New Jersey, 1998 and in "Encyclopedia of Surfac-tants," Vol. I-III , Chemical Publishing Co., New York, 1980-81. Surface active agents include, but are not limited to, alkyl sulfate salts, such as diethanolammonium lauryl sulfate; alkarylarylsulfonate salts, such as calcium dodecylbenzenesulfonate; alkylphenol-alkylene oxide addition products, such as nonylphenol-Cw ethoxylate; alcohol-alkylene oxide addition products, such as tridecyl alcohol-C16 ethoxylate; soaps, such as sodium stearate; alkyl naphthalenesulfonate salts, such as sodium dibutylnaphthalenesulfonate; dialkyl sulfosuccinate salt esters, such as sodium di (2-ethylhexyl) sulfosuccinate; sorbitol esters, such as sorbitol oleate; quaternary amines, such as lauryl trimethylammonium chloride; polyethylene glycol fatty acid esters, such as polyethylene glycol stearate; block copolymers of ethylene oxide and propylene oxide; mono and dialkyl phosphate ester salts; vegetable or seed oils, such as soybean oil, rapeseed / canola oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, flaxseed oil , palm oil, peanut oil, sunflower oil, sesame oil, tung oil, and the like; and esters of the above vegetable oils, and, in certain embodiments, methyl esters.
[0085] In some embodiments, these materials, such as seed and vegetable oils and their esters, can be used interchangeably as an agricultural adjuvant, as a liquid vehicle, or as a surface active agent.
[0086] Other exemplary additives in the compositions provided herein include, but are not limited to, compatibilizing agents, antifoaming agents, sequestering agents, neutralizing agents and buffers, corrosion inhibitors, dyes, odorants, diffusion, penetration aids, adhesion agents, dispersing agents, thickening agents, freezing point depressants, antimicrobial agents, and the like. The compositions can also contain other compatible components, for example, other herbicides, plant growth regulators, fungicides, insecticides, and the like, and can be formulated with liquid or solid fertilizers, particulate fertilizer vehicles, such as ammonium nitrate, urea , and the like.
[0087] In some embodiments, the concentration of active ingredients in the compositions described here is from about 0.0005 to 98 weight percent. In some embodiments, the concentration is from about 0.0006 to 90 weight percent. In compositions designed to be employed as concentrates, the active ingredients, in certain embodiments, are present in a concentration from about 0.1 to 98 weight percent, and in certain embodiments, about 0.5 to 90 percent in weight. Such compositions are, in certain embodiments, diluted with an inert carrier, such as water, prior to application. The diluted compositions usually applied to weeds, or at the site of weeds, contain, in certain embodiments, about 0.0006 to 3.0 percent by weight of active ingredient and, in certain embodiments, contain about 0.01 to 1.0 weight percent.
[0088] The present compositions can be applied to weeds, or to their locations, by the use of conventional soil or aerial dusters, sprayers, and granule applicators, by addition to irrigation or water from rice fields, and by other means conventionally known to those skilled in the art.
[0089] The embodiments described and examples that follow are for illustrative purposes, and are not intended to limit the scope of the claims. Other modifications, uses, or combinations with respect to the compositions described herein, will be apparent to one skilled in the art without departing from the spirit and scope of the claimed object matter. Examples
[0090] The results in Examples I and II are greenhouse test results. Example I. Evaluation of Herbicide Mixtures Applied by Post-emergence Foliar Application for Weed Control in Direct Seeded Rice
[0091] Seeds or "grains" of the desired test plant species were planted in a soil matrix prepared by mixing a slime or sandy loamy soil (eg 28.6 percent sludge, 18.8 percent clay, and 52.6 percent sand, with a pH of about 5.8, and an organic matter content of about 1.8 percent), and limestone grain in a ratio of 80 to 20. The soil matrix was contained in plastic pots with a volume of 1 quarter and a surface area of 83.6 square centimeters (cm2). When required to ensure good germination and healthy plants, a fungicide treatment and / or other chemical or physical treatment was applied. The plants were grown for 8-22 days in a greenhouse with a photoperiod of approximately 14 hours that was maintained at about 29 ° C during the day and 26 ° C at night. Nutrients (Peters Excel® 15-5-15 5-Ca 2-Mg and iron chelate) were applied to the irrigation solution as needed, and water was added on a regular basis. Additional lighting was provided with 100 watt metal halide lamps as needed. The plants were used for testing when they reached the first to the fourth true leaf stage.
[0092] Treatments consisting of 4- amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridine-2-carboxylic acid or esters (Compound A) , each formulated as a SC (suspension concentrate), and various herbicidal components alone and in combination. Compound Form A was applied on an acid equivalent basis.
[0093] The forms of compound A (compound of Formula I) tested include:

[0094] Other herbicidal components were applied on an active ingredient basis and included the halosulfuron-methyl acetate-synthase (ALS) inhibiting herbicides formulated as Permit® 75 WDG, pirazosulfuron-ethyl formulated as Agreen® WG or Sirius® G , and the VLCFA inhibiting herbicide esprocarb (technical grade material).
[0095] The treatment requirements were calculated based on the rates being tested, the concentration of active ingredient or acid equivalent in the formulation, and an application volume of 12 mL at a rate of 187 L / ha.
[0096] For treatments comprised of formulated compounds, measured amounts of compounds were individually placed in 25 ml glass bottles, and diluted in a volume of 1.25% (v / v) of concentrated Agri-Dex® cultivation oil for get 12X of stock solutions. If a test compound does not readily dissolve, the mixture was heated and / or sonicated. Application solutions were prepared by adding an appropriate amount of each stock solution (for example, 1 mL) and diluted to the appropriate final concentrations with the addition of 10 mL of a 1.25% aqueous mixture (v / v) cultivated oil concentrate, so that the final spray solutions contain 1.25 +/- 0.05% (v / v) cultivated oil concentrate.
[0097] For treatments comprised of technical compounds, heavy amounts can be placed individually in 25 ml glass vials, and dissolved in a 97: 3 v / v volume of acetone / DMSO to obtain 12X of stock solutions. If a test compound does not readily dissolve, the mixture can be heated and / or sonicated. Application solutions can be prepared by adding an appropriate amount of each stock solution (for example, 1 ml), and diluted to the appropriate final concentrations with the addition of 10 ml of a 1.5% (v / v) aqueous mixture ) of cultivated oil concentrate so that the final spray solutions contain 1.25% (v / v) of cultivated oil concentrate. When technical materials are used, concentrated stock solutions can be added to the spray solutions so that the final concentrations of acetone and DMSO in the application solutions are 16.2% and 0.5%, respectively.
[0098] For treatments comprised of technical and formulated compounds, heavy amounts of the technical materials were individually placed in 25 mL glass flasks, and dissolved in a 97: 3 v / v volume of acetone / DMSO to obtain 12X of stock solutions, and measured quantities of the formulated compounds were placed individually in 25 ml glass bottles, and diluted in a volume of 1.5% (v / v) of cultivated oil or water concentrate, to obtain 12X of solutions of stock. If a test compound does not readily dissolve, the mixture was heated and / or sonicated. Application solutions were prepared by adding an appropriate amount of each stock solution (for example, 1 ml), and diluted to the appropriate final concentrations with the addition of an appropriate amount of a 1.5% (v / v) cultivated oil concentrate so that the final spray solutions contain 1.25% (v / v) cultivated oil concentrate. As required, additional water and / or 97: 3 v / v acetone / DMSO was added to the individual application solutions so that the final concentrations of acetone and DMSO of the application solutions being compared were 8.1% and 0.25 %, respectively.
[0099] All stock solutions and application solutions were visually inspected for compatibility of the compound before application. Spray solutions were applied to the plant material with a main mandari screening sprayer equipped with 8002E nozzles calibrated to distribute 187 L / ha over an application area of 0.503 m2 at a spray height of 18 to 20 inches (46 to 50 cm) ) above the average plant crown height. The control plants were sprayed in the same way with the solvent test.
[00100] The treated plants and control plants were placed in a greenhouse, as described above, and dehydrated by sub-rooting to prevent washing of the test compounds. After approximately 3 weeks, the condition of the test plants, as compared to that of untreated plants, was determined visually and classified and, a scale of 0 to 100 percent where 0 corresponds to no damage or growth inhibition, and 100 corresponds to to complete death.
[00101] Colby's equation was used to determine the expected herbicidal effects from the mixtures (Colby, S.R. 1967. Calculation of the synergistic and antagonistic response of herbicide combinations. Weeds 15: 20-22).
[00102] The following equation was used to calculate the expected activity of mixtures containing two active ingredients, A and B: Expected = A + B - (A x B / 100) A = observed effectiveness of active ingredient A at the same concentration as used in the mixture. B = observed effectiveness of active ingredient B at the same concentration as used in the mixture.
Tabela 2. Atividade sinérgica de Composto A de Éster ben zílico Aplicado por Aplicação Foliar e Composições herbicidas de Halosulfuron-metila em Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 3. Atividade sinérgica de Composto A éster n-butílico Aplicado por Aplicação Foliar e Composições herbicidas de Halosulfuron-metila em Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 4. Atividade sinérgica de Composto A Ácido Aplicado por Aplicação Foliar e Composições herbicidas de Pirazosulfuron- etila (Agreen® WG) em Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 5. Atividade sinérgica de Composto A Éster benzílico Aplicado por Aplicação Foliar e Composições herbicidas de Pirazosulfuron-etila (Agreen® WG) em Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 6. Atividade sinérgica de Composto A éster n- butílico Aplicado por Aplicação Foliar e Composições herbicidas de Pirazosulfuron-etila (Agreen® WG) em Controle de Erva Daninha em um Sistema de Cultivo de de Arroz. Tabela 7. Atividade sinérgica de Composto A Ácido Aplica do por Aplicação Foliar e Composições herbicidas de Esprocarb em Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 8. Atividade sinérgica de Composto A Éster benzílico Aplicado por Aplicação Foliar e de Composições herbicidas de Esprocarb em Controle de Erva Daninha em um Sistema de Cultivo de Arroz.
[00103] The tested compounds, application rates employed, tested plant species, and results are given in Tables 1 to 8. Table 1. Synergistic activity of Acid Compound Applied by Foliar Application and Halosulfuron-methyl herbicidal compositions in Control of Weed in a Rice Growing System. Table 2. Synergistic activity of benzyl ester compound A applied by foliar application and halosulfuron-methyl herbicidal compositions in weed control in a rice cultivation system. Table 3. Synergistic activity of Compound A n-butyl ester Applied by Foliar Application and Halosulfuron-methyl herbicidal compositions in Weed Control in a Rice Growing System. Table 4. Synergistic activity of Acid Compound Applied by Foliar Application and Herbicidal Compositions of Pirazosulfuronethyl (Agreen® WG) in Weed Control in a Rice Cultivation System. Table 5. Synergistic activity of Compound A Benzyl Ester Applied by Foliar Application and Herbicidal Compositions of Pirazosulfuron-ethyl (Agreen® WG) in Weed Control in a Rice Growing System. Table 6. Synergistic activity of Compound A n-butyl ester Applied by Foliar Application and Herbicidal Compositions of Pirazosulfuron-ethyl (Agreen® WG) in Weed Control in a Rice Growing System. Table 7. Synergistic activity of Compound A Applied Acid by Foliar Application and Herbicidal Compositions of Esprocarb in Weed Control in a Rice Growing System. Table 8. Synergistic activity of Compound A Benzyl Ester Applied by Foliar Application and of Esprocarb Herbicidal Compositions in Weed Control in a Rice Cultivation System.
Example II. Evaluation of Herbicide Mixtures Applied in Water for Weed Control in Transplanted Rice Fields
[00104] Weed seeds or "grains" of the desired test plant species were planted in plowed soil (mud) prepared by mixing a crushed non-sterile mineral soil (50.5 percent sludge, 25.5 percent clay , and 24 percent sand, with a pH of about 7.6, and an organic matter content of about 2.9 percent), and water at a volumetric ratio of 1: 1. The prepared sludge was dispensed in 365 mL aliquots in 16 oz (oz) unperforated plastic pots with a surface area of 86.59 square centimeters (cm2) leaving a free space of 3 centimeters (cm) in each Mud pot was allowed dry overnight before planting or transplanting. The rice seeds were planted in a Sun Gro Metro Mix® 306 planting mixture, which typically has a pH of 6.0 to 6.8, and an organic matter content of about 30 percent, in plastic trays. The seedlings in the second or third stage of the growth leaf were transplanted in 840 mL of mud contained in 32 ounce (oz) unperforated plastic pots with a surface area of 86.59 cm2 4 days before the application of the herbicide. The rice field was created by filling the free space of the pots with 2.5 to 3 cm of water. When required to ensure good germination and healthy plants, a fungicide treatment and / or other chemical or physical treatment was applied. The plants were grown for 4-22 days in a greenhouse with an approximate 14-hour photoperiod that was maintained at about 29 ° C during the day and 26 ° C at night. Nutrients were added as Osmocote® (19: 6: 12, N: P: K + minor nutrients) to 2 g per 16 oz pot and 4 g per 0.95 L (32 oz) pot (oz). Water was added on a regular basis to keep the paddy flooded, and additional lighting was provided with 100 watt metal halide lamps as needed. The plants were used for testing when they reached the first to the fourth true leaf stage.
[00105] The treatments consisted of 4- amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) pyridine-2-carboxylic acid or esters (compound A) each formulated as a SC (suspension concentrate) and various herbicidal components alone and in combination. Compound A forms were applied on an acid equivalent basis.
[00106] The forms of compound A (compound of Formula I) tested include:

[00107] Other herbicidal components were applied on an active ingredient basis, and included aceto-lactate synthase (ALS) inhibiting herbicides formulated as Permit® 75 WDG, pirazosulfuron-ethyl formulated as Agreen® WG or Sirius® G, and herbicide inhibition of VLCFA esprocarb (technical grade material).
[00108] The treatment requirements for each herbicide compound or component were calculated based on the rates being tested, the concentration of active ingredient or acid equivalent in the formulation, an application volume of 2 mL per component per pot, and an application area of 86.59 cm2 per pot.
[00109] For the formulated compounds, a measured quantity was placed in an individual glass bottle of 100 or 200 mL, and was dissolved in a volume of 1.25% (v / v) of Agri-Dex cultivation oil concentrate ® for application solutions. If the test compound did not readily dissolve, the mixture was heated and / or sonicated.
[00110] For technical grade compounds, a heavy amount was placed in an individual glass bottle of 100 to 200 mL, and was dissolved in a volume of acetone to obtain concentrated stock solutions. If the test compound did not readily dissolve, the mixture was heated and / or sonicated. The concentrated stock solutions obtained were diluted with an equivalent volume of an aqueous mixture containing 2.5% (v / v) of cultivated oil concentrate so that the final application solutions contain 1.25% (v / v) of cultivated oil concentrate.
[00111] Applications were made by injection with a pipette of appropriate amounts of the application solutions, individually and sequentially, in the aqueous layer of rice. Control plants were treated in the same way with the solvent test. Applications were made so that all treated plant material received the same concentrations of acetone and oil concentrate.
[00112] The treated plants and control plants were placed in a greenhouse as described above, and water was added as needed, to maintain a flood of rice. After approximately 3 weeks, the condition of the test plants, as compared to that of untreated plants, was determined visually and rated on a scale of 0 to 100 percent where 0 corresponds to no damage or growth inhibition, and 100 corresponds to death complete.
[00113] Colby's equation was used to determine the expected herbicidal effects from the mixtures (Colby, S.R. 1967. Calculation of the synergistic and antagonistic response of herbicide combinations. Weeds 15: 20-22).
[00114] The following equation was used to calculate the expected activity of mixtures containing two active ingredients, A and B: Expected = A + B - (A x B / 100) A = observed effectiveness of active ingredient A at the same concentration as used in the mixture. B = observed effectiveness of active ingredient B at the same concentration as used in the mixture.
Tabela 10. Atividade sinérgica de Aplicações Em Água de Composto A Éster benzílico e Composições herbicidas de Halosulfuron-metila no Controle de Erva Daninha em um Sistema de Cultivo de Arroz.  Tabela 11. Atividade sinérgica de Aplicações Em Agua de Composto A éster n-butílico e Composições herbicidas de Halosulfuron-metila no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 12. Atividade sinérgica de Aplicações Em Água de Composto A Ácido e Pirazosulfuron-etila (Sirius® G) Composições herbicidas no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 13. Atividade sinérgica de Aplicações Em Agua de Composto A Ácido e Pirazosulfuron-etila (Agreen® WG) Composições herbicidas no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 14. Atividade sinérgica de Aplicações Em Água de Composto A éster n-butílico e Pirazosulfuron-etila (Sirius® G) Composições herbicidas no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 15. Atividade sinérgica de Aplicações Em Água de Composto A Éster benzílico e Pirazosulfuron-etila (Sirius® G) Composições herbicidas no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 16. Atividade sinérgica de Aplicações Em Água de Composto A Éster benzílico e Pirazosulfuron-etila (Agreen® WG) Composições herbicidas no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 17. Atividade sinérgica de Aplicações Em Água de Composto A Ácido e Composições herbicidas de Esprocarb no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. Tabela 18. Atividade sinérgica de Aplicações Em Agua de Composto A Éster benzílico e Composições herbicidas de Esprocarb no Controle de Erva Daninha em um Sistema de Cultivo de Arroz. 
[00115] Some of the tested compounds, applied application rates, tested plant species, and results, are given in Tables 9 to 18. Table 9. Synergistic Activity of Acid Compound Water Applications and Halosulfuron Herbicidal Compositions -methyl in Weed Control in a Rice Cultivation System. Table 10. Synergistic activity of Water Applications of Benzyl Ester Compound and Halosulfuron-methyl Herbicide Compositions in Weed Control in a Rice Growing System. Table 11. Synergistic activity of Applications in Water of Compound A n-butyl ester and Herbicidal Compositions of Halosulfuron-methyl in Weed Control in a Rice Cultivation System. Table 12. Synergistic activity of Water Applications of Acid Compound and Pirazosulfuron-ethyl (Sirius® G) Herbicidal compositions in the Control of Weed in a Rice Cultivation System. Table 13. Synergistic activity of Acid Compound Water and Pirazosulfuron-ethyl (Agreen® WG) Herbicidal compositions in the Control of Weed in a Rice Growing System. Table 14. Synergistic activity of Water Applications of Compound A n-butyl ester and Pirazosulfuron-ethyl (Sirius® G) Herbicidal compositions in Weed Control in a Rice Growing System. Table 15. Synergistic activity of Water Applications of Compound A Benzyl ester and Pirazosulfuron-ethyl (Sirius® G) Herbicidal compositions in the Control of Weed in a Rice Growing System.Table 16. Synergistic activity of Water Applications of Benzyl Ester Compound and Pirazosulfuron-ethyl (Agreen® WG) Herbicidal compositions in Weed Control in a Rice Growing System.Table 17. Synergistic Activity of Water Applications of Acid Compound and Esprocarb Herbicide Compositions for Weed Control in a Rice Growing System. Table 18. Synergistic activity of Water Applications of Benzyl Ester Compound and Esprocarb Herbicide Compositions in Weed Control in a Rice Growing System.

权利要求:
Claims (10)
[0001]
ou benzil éster do mesmo, e (b) um composto selecionado a partir do grupo consistindo em halosulfuron-metila, pirazosulfuron-etila e esprocarb, sendo que quando: (c) é esprocarb, a razão em peso de (a) para (b) é de 1:6 a 1:48; (d) é halosulfuron-metila, a razão em peso de (a) para (b) é de 4:1 a 1:4; (e) é pirazosulfuron-etila, a razão em peso de (a) para (b) é de 4:1 a 1:14.1. Herbicidal composition, characterized by the fact that it comprises a herbicidally effective amount of: (a) a compound of Formula (I) or benzyl ester thereof, and (b) a compound selected from the group consisting of halosulfuron-methyl, pirazosulfuron-ethyl and esprocarb, where when: (c) is esprocarb, the weight ratio from (a) to (b ) is 1: 6 to 1:48; (d) is halosulfuron-methyl, the weight ratio of (a) to (b) is 4: 1 to 1: 4; (e) is pirazosulfuron-ethyl, the weight ratio of (a) to (b) is 4: 1 to 1:14.
[0002]
2. Composition according to claim 1, characterized by the fact that (a) is the benzyl ester of the compound of Formula (I).
[0003]
Composition according to claim 1 or 2, characterized by the fact that it also comprises an agriculturally acceptable adjuvant or vehicle.
[0004]
Composition according to any one of claims 1 to 3, characterized in that it further comprises an herbicide protection agent.
[0005]
5. Method for controlling undesirable vegetation, characterized by the fact that it comprises the stage of contacting a plant, the plant being an undesirable vegetation or its location, soil or water, with soil or water allowing growth of undesirable vegetation, with a herbicidally effective amount of a composition, as defined in any one of claims 1 to 4.
[0006]
6. Method, according to claim 5, characterized by the fact that the undesirable vegetation is controlled in direct sown rice, sown in water, and transplanted, cereals, wheat, barley, oats, rye, sorghum, corn / maize, cane -sugar, sunflower, rapeseed, canola, sugar beet, soy, cotton, pineapple, pasture, grassland, pasture land, fallow, peat, vineyards and orchards, aquatic, industrial vegetation management (IVM), or easements (ROW ).
[0007]
7. Method according to claim 5 or 6, characterized by the fact that (a) and (b) are applied pre-emergently to the plant or crop.
[0008]
Method according to any one of claims 5 to 7, characterized in that the undesirable vegetation is controlled in glyphosate, 5-enolpyruvylshikimato-3-phosphatase (EPSP) synthase, glufosinate, glutamine synthase, dicamba inhibitor , phenoxy auxin, pyridyloxy auxin, synthetic auxin, auxin transport inhibitor, aryloxyphenoxypropionate, cyclohexanedione, phenylpyrazoline, acetyl CoA carboxylase inhibitor (ACCase), imidazolinone-, sulfonylurea, pyrimidinyl thiozolinate, sulfonylamine, triazolone ) or acetohydroxy acid synthase (AHAS), 4-hydroxyphenylpyruvate dioxigenase (HPPD) inhibitor, phytoene desaturase inhibitor, carotenoid biosynthesis inhibitor, protoporphyrinogen oxidase inhibitor (PPO), cellulose biosynthesis inhibitor, cellulose inhibitor mitosis, microtubule inhibitor, very long chain fatty acid inhibitor, fatty acid and lipid biosynthesis inhibitor, i photosystem I inhibitor, photosystem II inhibitor, triazine, or bromoxynil tolerant crops.
[0009]
9. Method, according to claim 8, characterized by the fact that the tolerant crop has multiple or stacked treatments that confer tolerance to multiple herbicides or multiple modes of action.
[0010]
Method according to any one of claims 5 to 9, characterized in that the undesirable vegetation comprises a herbicide resistant or tolerant plant.

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BR102014001750A2|2015-10-27|herbicidal compositions comprising 4-amino-3-chloro-6- | pyridine-2-carboxylic acid or a derivative thereof and certain triazolopyrimidine sulfonamides

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BR102014001780A2|2015-08-25|Herbicidal compositions comprising 4-amino-3-chloro-6- | pyridine-2-carboxylic acid or a derivative thereof and propyzamide

---

BR102014001759A2|2015-08-25|Herbicidal compositions and methods for use of combinations of 4-amino-3-chloro-6- | pyridine-2-carboxylic acid or a derivative thereof and an herbicide aryloxyphenoxy propionate inhibitor from accase

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BR112021008350A2|2021-08-03|compositions comprising halauxifene and other herbicides and methods thereof

---

BR112021008338A2|2021-08-03|compositions comprising halauxifen and other herbicides and their methods

---

BR102018016299A2|2019-03-19|HERBICIDE COMPOSITIONS UNDERSTANDING 4-AMINO-3-CHLOR-5-FLUORO-6- | PYRIDINE-2-CARBOXYLIC ACID OR A DERIVATIVE OF THE SAME AND TEMBOTRION AND / OR TOPRAME

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BR102016017074A2|2017-01-31|herbicidal compositions comprising 4-amino-3-chloro-6- | -5-fluoropyridine-2-carboxylic acid or a derivative thereof and chloroquate chloride

同族专利:

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公开号 | 公开日

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US8809232B2|2014-08-19|

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SG11201500540XA|2015-02-27|

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TWI616139B|2018-03-01|

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EP2877009A4|2016-03-30|

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CN104661523A|2015-05-27|

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WO2014018412A1|2014-01-30|

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IN2015DN01374A|2015-07-03|

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SA113340744B1|2015-07-07|

---

WO2014018412A9|2014-05-22|

---

CN104661523B|2017-11-07|

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US20140031216A1|2014-01-30|

---

UA113994C2|2017-04-10|

---

MX2015001133A|2015-09-07|

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AU2013293259A1|2015-03-05|

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DK2877009T3|2019-04-08|

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TW201406297A|2014-02-16|

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IL236857D0|2015-03-31|

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EP2877009A1|2015-06-03|

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ZA201501142B|2017-07-26|

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JP2015528016A|2015-09-24|

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UY34926A|2014-02-28|

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HK1209282A1|2016-04-01|

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KR102102826B1|2020-04-22|

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CL2015000189A1|2015-04-24|

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BR102013018660A2|2015-03-03|

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RU2015105829A|2016-09-10|

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ES2717284T3|2019-06-20|

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IL236857A|2019-07-31|

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RU2630705C2|2017-09-12|

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EP2877009B1|2019-01-02|

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CO7200274A2|2015-02-27|

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PH12015500154A1|2015-03-16|

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KR20150036749A|2015-04-07|

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AU2013293259B2|2017-05-11|

---

PT2877009T|2019-04-26|

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AR091884A1|2015-03-04|

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JP6367191B2|2018-08-01|

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US8912120B2|2012-07-24|2014-12-16|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and synthetic auxin herbicides|

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US8889591B2|2012-07-24|2014-11-18|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and bromobutide, daimuron, oxaziclomefone or pyributicarb|

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US8846570B2|2012-07-24|2014-09-30|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and microtubule inhibiting herbicides|

---

US8901035B2|2012-07-24|2014-12-02|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and cellulose biosynthesis inhibitor herbicides|

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US8895470B2|2012-07-24|2014-11-25|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and glyphosate or glufosinate|

---

US8912121B2|2012-07-24|2014-12-16|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and certain PS II inhibitors|

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US8871681B2|2012-07-24|2014-10-28|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and certain sulfonylureas|

---

US8906826B2|2012-07-24|2014-12-09|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and imidazolinones|

---

US8841233B2|2012-07-24|2014-09-23|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and 4-hydroxyphenyl-pyruvate dioxygenase inhibitors|

---

US8883682B2|2012-07-24|2014-11-11|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and auxin transport inhibitors|

---

US8791048B2|2012-07-24|2014-07-29|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and clomazone|

---

US9644469B2|2012-07-24|2017-05-09|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides|

---

US8916499B2|2012-07-24|2014-12-23|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and a protoporphyrinogen oxidase inhibitor|

---

US8796177B2|2012-07-24|2014-08-05|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and acetyl-CoA carboxylase inhibitors|

---

US8906825B2|2012-07-24|2014-12-09|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and triazolopyrimidine sulfonamides|UA94351C2|2007-08-27|2011-04-26|ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи|Synergistic herbicidal composition comprising certain pyridine or pyrimidine carboxylic acids and certain herbicides for cereals and rice|

---

US8841233B2|2012-07-24|2014-09-23|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and 4-hydroxyphenyl-pyruvate dioxygenaseinhibitors|

---

US9644469B2|2012-07-24|2017-05-09|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides|

---

US8883682B2|2012-07-24|2014-11-11|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and auxin transport inhibitors|

---

US8889591B2|2012-07-24|2014-11-18|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and bromobutide, daimuron, oxaziclomefone or pyributicarb|

---

US8912120B2|2012-07-24|2014-12-16|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and synthetic auxin herbicides|

---

US8796177B2|2012-07-24|2014-08-05|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and acetyl-CoA carboxylaseinhibitors|

---

US8871681B2|2012-07-24|2014-10-28|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and certain sulfonylureas|

---

US8871680B2|2012-07-24|2014-10-28|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and a di-methoxy-pyrimidine and derivatives thereof|

---

US8906826B2|2012-07-24|2014-12-09|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and imidazolinones|

---

US8916499B2|2012-07-24|2014-12-23|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and a protoporphyrinogen oxidase inhibitor|

---

US8906825B2|2012-07-24|2014-12-09|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and triazolopyrimidine sulfonamides|

---

US8846570B2|2012-07-24|2014-09-30|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and microtubule inhibiting herbicides|

---

US8901035B2|2012-07-24|2014-12-02|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and cellulose biosynthesis inhibitor herbicides|

---

US8895470B2|2012-07-24|2014-11-25|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and glyphosate or glufosinate|

---

US8912121B2|2012-07-24|2014-12-16|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof and certain PS II inhibitors|

---

US8791048B2|2012-07-24|2014-07-29|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and clomazone|

---

US20140031224A1|2012-07-24|2014-01-30|Dow Agrosciences Llc|Safened herbicidal compositions including 4-amino-3-chloro-5-fluoro-6-pyridine-2-carboxylic acid or a derivative thereof for use in rice|

---

AP2015008776A0|2013-03-15|2015-09-30|Dow Agrosciences Llc|Safened herbicidal compositions including pyridine-2-carboxylic acid derivatives for use in corn |

---

US9730445B2|2013-03-15|2017-08-15|Dow Agrosciences Llc|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and fungicides|

---

US8841234B1|2013-03-15|2014-09-23|Dow Agrosciences, Llc.|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and fungicides|

---

CN107787997A|2016-08-30|2018-03-13|燕化永乐（乐亭）生物科技有限公司|A kind of complex weedicide|

---

US11109588B2|2019-02-19|2021-09-07|Gowan Company, L.L.C.|Stable liquid formulations and methods of using the same|

法律状态:
2015-03-03| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|

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2016-10-11| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-09-11| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

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2019-01-08| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

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2019-11-05| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

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2020-04-07| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2020-10-27| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/07/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US201261675110P| true| 2012-07-24|2012-07-24|

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US61/675.110|2012-07-24|

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US13/834.326|2013-03-15|

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US13/834,326|US8809232B2|2012-07-24|2013-03-15|Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- pyridine-2-carboxylic acid or a derivative thereof and halosulfuron, pyrazosulfuron and esprocarb|

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